Crystal engineering with heteroboranes. II. 1,2-Dicarboxy-1,2-dicarba-closo-dodecaborane(12) ethanol hemisolvate

Ulaganathan Venkatasubramanian; David Ellis; Georgina M. Rosair; Alan J. Welch

doi:10.1107/S0108270103017608

Crystal engineering with heteroboranes. II. 1,2-Dicarboxy-1,2-dicarba-closo-dodecaborane(12) ethanol hemisolvate

Ulaganathan Venkatasubramanian
, David Ellis
, Georgina M. Rosair
, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The title compound, 1,2-(COOH)₂-1,2-closo-C₂B ₁₀H₁₀·0.5C₂H₆O or C ₄H₁₂B₁₀O₄·0.5C ₂H₆O, forms a tetramer by incorporating ethanol (solvent) molecules through hydrogen bonding. Two eight-membered rings [graph set R ₂²(8)] are formed by hydrogen bonding between two carboxylic acid groups, whereas two ten-membered rings [R₃³(10)] are formed by hydrogen bonding between two carboxylic acid groups and the OH group of an ethanol molecule (solvent). Two crystallographically independent tetramers are present in the crystal structure.

Original language	English
Pages (from-to)	o559-o561
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	59
Issue number	10
DOIs	https://doi.org/10.1107/S0108270103017608
Publication status	Published - Oct 2003

Access to Document

10.1107/S0108270103017608

Cite this

@article{358404e57541421089302f8ba93c54f6,

title = "Crystal engineering with heteroboranes. II. 1,2-Dicarboxy-1,2-dicarba-closo-dodecaborane(12) ethanol hemisolvate",

abstract = "The title compound, 1,2-(COOH)2-1,2-closo-C2B 10H10·0.5C2H6O or C 4H12B10O4·0.5C 2H6O, forms a tetramer by incorporating ethanol (solvent) molecules through hydrogen bonding. Two eight-membered rings [graph set R 22(8)] are formed by hydrogen bonding between two carboxylic acid groups, whereas two ten-membered rings [R33(10)] are formed by hydrogen bonding between two carboxylic acid groups and the OH group of an ethanol molecule (solvent). Two crystallographically independent tetramers are present in the crystal structure.",

author = "Ulaganathan Venkatasubramanian and David Ellis and Rosair, \{Georgina M.\} and Welch, \{Alan J.\}",

year = "2003",

month = oct,

doi = "10.1107/S0108270103017608",

language = "English",

volume = "59",

pages = "o559--o561",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "1600-5759",

publisher = "International Union of Crystallography",

number = "10",

}

TY - JOUR

T1 - Crystal engineering with heteroboranes. II. 1,2-Dicarboxy-1,2-dicarba-closo-dodecaborane(12) ethanol hemisolvate

AU - Venkatasubramanian, Ulaganathan

AU - Ellis, David

AU - Rosair, Georgina M.

AU - Welch, Alan J.

PY - 2003/10

Y1 - 2003/10

N2 - The title compound, 1,2-(COOH)2-1,2-closo-C2B 10H10·0.5C2H6O or C 4H12B10O4·0.5C 2H6O, forms a tetramer by incorporating ethanol (solvent) molecules through hydrogen bonding. Two eight-membered rings [graph set R 22(8)] are formed by hydrogen bonding between two carboxylic acid groups, whereas two ten-membered rings [R33(10)] are formed by hydrogen bonding between two carboxylic acid groups and the OH group of an ethanol molecule (solvent). Two crystallographically independent tetramers are present in the crystal structure.

AB - The title compound, 1,2-(COOH)2-1,2-closo-C2B 10H10·0.5C2H6O or C 4H12B10O4·0.5C 2H6O, forms a tetramer by incorporating ethanol (solvent) molecules through hydrogen bonding. Two eight-membered rings [graph set R 22(8)] are formed by hydrogen bonding between two carboxylic acid groups, whereas two ten-membered rings [R33(10)] are formed by hydrogen bonding between two carboxylic acid groups and the OH group of an ethanol molecule (solvent). Two crystallographically independent tetramers are present in the crystal structure.

UR - https://www.scopus.com/pages/publications/0242663967

U2 - 10.1107/S0108270103017608

DO - 10.1107/S0108270103017608

M3 - Article

SN - 1600-5759

VL - 59

SP - o559-o561

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 10

ER -

Crystal engineering with heteroboranes. II. 1,2-Dicarboxy-1,2-dicarba-closo-dodecaborane(12) ethanol hemisolvate

Abstract

Access to Document

Other files and links

Fingerprint

Cite this