Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes

Mailer Cameron, Brian G. Gowenlock, Guiseppe Vasapollo

Research output: Contribution to journalArticle

Abstract

Complexes of 4-substituted nitrosobenzenes with palladium dichloride have been prepared and studied by solid state CP/MAS 13C NMR spectroscopy. The results obtained are discussed in terms of the unique property of the nitroso group based upon its high p-electron accepting character. It is shown that this property is maintained when the NO group undergoes sN coordination to palladium in contrast to recent evidence that pNO coordination to molybenum removes this property. The effect of coordination upon the chemical shifts of the other ring carbons is also discussed. © 1995.

Original languageEnglish
Pages (from-to)2087-2090
Number of pages4
JournalPolyhedron
Volume14
Issue number15-16
Publication statusPublished - Aug 1995

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Coordination Complexes
Palladium
Chemical shift
Nuclear magnetic resonance spectroscopy
Carbon
Electrons
nitrosobenzene
palladium chloride

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Cameron, M., Gowenlock, B. G., & Vasapollo, G. (1995). Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes. Polyhedron, 14(15-16), 2087-2090.
Cameron, Mailer ; Gowenlock, Brian G. ; Vasapollo, Guiseppe. / Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes. In: Polyhedron. 1995 ; Vol. 14, No. 15-16. pp. 2087-2090.
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Cameron, M, Gowenlock, BG & Vasapollo, G 1995, 'Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes', Polyhedron, vol. 14, no. 15-16, pp. 2087-2090.

Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes. / Cameron, Mailer; Gowenlock, Brian G.; Vasapollo, Guiseppe.

In: Polyhedron, Vol. 14, No. 15-16, 08.1995, p. 2087-2090.

Research output: Contribution to journalArticle

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Cameron M, Gowenlock BG, Vasapollo G. Coordination complexes of palladium dichloride with 4-substituted nitrosobenzenes. Polyhedron. 1995 Aug;14(15-16):2087-2090.