Coordination complexes of metal halides with substituted 4-nitrosoanilines

Mailer Cameron; Brian G. Gowenlock; Giuseppe Vasapollo

Coordination complexes of metal halides with substituted 4-nitrosoanilines

Mailer Cameron, Brian G. Gowenlock, Giuseppe Vasapollo

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Complexes of substituted p-nitrosoanilines with metal halides have been prepared and studied by solid state CP/MAS NMR spectroscopy. The ¹³C and ¹⁵N NMR spectra give information concerning the structural changes that occur in the C-nitrosoligand on coordination to metals. Supplementary information is provided in some cases by ¹¹⁹Sn and ¹¹³Cd NMR spectra and also by Mössbauer spectroscopy for Sn complexes. It is shown that it is not possible to distinguish between s_N and s_O coordination on the basis of IR spectroscopy. © 1994.

Original language	English
Pages (from-to)	1371-1377
Number of pages	7
Journal	Polyhedron
Volume	13
Issue number	9
Publication status	Published - May 1994

Cite this

@article{d2b2110dca5347c9a88a5e92ba145a0e,

title = "Coordination complexes of metal halides with substituted 4-nitrosoanilines",

abstract = "Complexes of substituted p-nitrosoanilines with metal halides have been prepared and studied by solid state CP/MAS NMR spectroscopy. The 13C and 15N NMR spectra give information concerning the structural changes that occur in the C-nitrosoligand on coordination to metals. Supplementary information is provided in some cases by 119Sn and 113Cd NMR spectra and also by M{\"o}ssbauer spectroscopy for Sn complexes. It is shown that it is not possible to distinguish between sN and sO coordination on the basis of IR spectroscopy. {\textcopyright} 1994.",

author = "Mailer Cameron and Gowenlock, {Brian G.} and Giuseppe Vasapollo",

year = "1994",

month = may,

language = "English",

volume = "13",

pages = "1371--1377",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "9",

}

TY - JOUR

T1 - Coordination complexes of metal halides with substituted 4-nitrosoanilines

AU - Cameron, Mailer

AU - Gowenlock, Brian G.

AU - Vasapollo, Giuseppe

PY - 1994/5

Y1 - 1994/5

N2 - Complexes of substituted p-nitrosoanilines with metal halides have been prepared and studied by solid state CP/MAS NMR spectroscopy. The 13C and 15N NMR spectra give information concerning the structural changes that occur in the C-nitrosoligand on coordination to metals. Supplementary information is provided in some cases by 119Sn and 113Cd NMR spectra and also by Mössbauer spectroscopy for Sn complexes. It is shown that it is not possible to distinguish between sN and sO coordination on the basis of IR spectroscopy. © 1994.

AB - Complexes of substituted p-nitrosoanilines with metal halides have been prepared and studied by solid state CP/MAS NMR spectroscopy. The 13C and 15N NMR spectra give information concerning the structural changes that occur in the C-nitrosoligand on coordination to metals. Supplementary information is provided in some cases by 119Sn and 113Cd NMR spectra and also by Mössbauer spectroscopy for Sn complexes. It is shown that it is not possible to distinguish between sN and sO coordination on the basis of IR spectroscopy. © 1994.

UR - http://www.scopus.com/inward/record.url?scp=0005980660&partnerID=8YFLogxK

M3 - Article

SN - 0277-5387

VL - 13

SP - 1371

EP - 1377

JO - Polyhedron

JF - Polyhedron

IS - 9

ER -

Coordination complexes of metal halides with substituted 4-nitrosoanilines

Abstract

Other files and links

Fingerprint

Cite this