Three complexes of platinum with C-nitroso compounds have been studied by 13C NMR spectroscopy. It has been shown that in all three cases there is a pronounced shift to higher frequency of C-NO and that for the two cases where this involves the t-butyl group the PtC coupling is evident. It is noted that this effect is stronger than for the coordination of some other ligands to platinum. © 1988.
|Number of pages||4|
|Journal||Journal of Organometallic Chemistry|
|Publication status||Published - 3 May 1988|