Coordination complexes of C-nitroso compounds. A 13C NMR study of some complexes of platinum with C-nitroso compounds

A. S F Boyd; Gavin Browne; Brian G. Gowenlock; Paul McKenna

Coordination complexes of C-nitroso compounds. A ¹³C NMR study of some complexes of platinum with C-nitroso compounds

A. S F Boyd, Gavin Browne, Brian G. Gowenlock, Paul McKenna

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Three complexes of platinum with C-nitroso compounds have been studied by ¹³C NMR spectroscopy. It has been shown that in all three cases there is a pronounced shift to higher frequency of C-NO and that for the two cases where this involves the t-butyl group the PtC coupling is evident. It is noted that this effect is stronger than for the coordination of some other ligands to platinum. © 1988.

Original language	English
Pages (from-to)	217-220
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	345
Issue number	1-2
Publication status	Published - 3 May 1988

Cite this

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title = "Coordination complexes of C-nitroso compounds. A 13C NMR study of some complexes of platinum with C-nitroso compounds",

abstract = "Three complexes of platinum with C-nitroso compounds have been studied by 13C NMR spectroscopy. It has been shown that in all three cases there is a pronounced shift to higher frequency of C-NO and that for the two cases where this involves the t-butyl group the PtC coupling is evident. It is noted that this effect is stronger than for the coordination of some other ligands to platinum. {\textcopyright} 1988.",

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T1 - Coordination complexes of C-nitroso compounds. A 13C NMR study of some complexes of platinum with C-nitroso compounds

AU - Boyd, A. S F

AU - Browne, Gavin

AU - Gowenlock, Brian G.

AU - McKenna, Paul

PY - 1988/5/3

Y1 - 1988/5/3

N2 - Three complexes of platinum with C-nitroso compounds have been studied by 13C NMR spectroscopy. It has been shown that in all three cases there is a pronounced shift to higher frequency of C-NO and that for the two cases where this involves the t-butyl group the PtC coupling is evident. It is noted that this effect is stronger than for the coordination of some other ligands to platinum. © 1988.

AB - Three complexes of platinum with C-nitroso compounds have been studied by 13C NMR spectroscopy. It has been shown that in all three cases there is a pronounced shift to higher frequency of C-NO and that for the two cases where this involves the t-butyl group the PtC coupling is evident. It is noted that this effect is stronger than for the coordination of some other ligands to platinum. © 1988.

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M3 - Article

SN - 0022-328X

VL - 345

SP - 217

EP - 220

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Coordination complexes of C-nitroso compounds. A ¹³C NMR study of some complexes of platinum with C-nitroso compounds

Abstract

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