Construction of an organic cage-based porous ionic liquid using an aminal tying strategy

Aiting Kai; Austin Mroz; Kim E. Jelfs; Andrew I. Cooper; Marc A. Little; Rebecca L. Greenaway

doi:10.1039/d5me00004a

Construction of an organic cage-based porous ionic liquid using an aminal tying strategy

Aiting Kai, Austin Mroz, Kim E. Jelfs, Andrew I. Cooper, Marc A. Little, Rebecca L. Greenaway^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Downloads (Pure)

Abstract

An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf₂]₆, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO₂ uptake, and its permanent porosity was confirmed using molecular dynamic simulations.

Original language	English
Journal	Molecular Systems Design and Engineering
Early online date	2 Apr 2025
DOIs	https://doi.org/10.1039/d5me00004a
Publication status	E-pub ahead of print - 2 Apr 2025

Access to Document

10.1039/d5me00004aLicence: CC BY

Download pdf
© The Royal Society of Chemistry and IChemE 2025.
Final published version, 721 KBLicence: CC BY

Cite this

@article{9c21ba88741d429ebdfabd27703cf7e8,

title = "Construction of an organic cage-based porous ionic liquid using an aminal tying strategy",

abstract = "An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf2]6, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO2 uptake, and its permanent porosity was confirmed using molecular dynamic simulations.",

author = "Aiting Kai and Austin Mroz and Jelfs, {Kim E.} and Cooper, {Andrew I.} and Little, {Marc A.} and Greenaway, {Rebecca L.}",

year = "2025",

month = apr,

day = "2",

doi = "10.1039/d5me00004a",

language = "English",

journal = "Molecular Systems Design and Engineering",

issn = "2058-9689",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Construction of an organic cage-based porous ionic liquid using an aminal tying strategy

AU - Kai, Aiting

AU - Mroz, Austin

AU - Jelfs, Kim E.

AU - Cooper, Andrew I.

AU - Little, Marc A.

AU - Greenaway, Rebecca L.

PY - 2025/4/2

Y1 - 2025/4/2

N2 - An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf2]6, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO2 uptake, and its permanent porosity was confirmed using molecular dynamic simulations.

AB - An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf2]6, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO2 uptake, and its permanent porosity was confirmed using molecular dynamic simulations.

UR - http://www.scopus.com/inward/record.url?scp=105002376104&partnerID=8YFLogxK

U2 - 10.1039/d5me00004a

DO - 10.1039/d5me00004a

M3 - Article

SN - 2058-9689

JO - Molecular Systems Design and Engineering

JF - Molecular Systems Design and Engineering

ER -

Construction of an organic cage-based porous ionic liquid using an aminal tying strategy

Abstract

Access to Document

Other files and links

Fingerprint

Cite this