Connected fluid evolution in fractured crystalline basement and overlying sediments, Pannonian Basin, SE Hungary

Attila Juhász, Tivadar M. Tóth, Karl Ramseyer, Albert Matter

    Research output: Contribution to journalArticle

    Abstract

    Uplifted crystalline basement highs have played an important role in the hydrologic history of the Pannonian Basin providing conduits for fluid migration during basin evolution. Petrographic, stable isotope, electron microprobe and fluid-inclusion studies support a five-step basin evolution; (1) formation of crystalline core-complexes, (2) percolation of meteoric water through shear zones, (3) basinwide thermal subsidence, (4) hydrologic inversion, and (5) tectonic inversion. Brittle fractures in the basement are the results of uplift during core complex formation and contain pyrite, kaolin, illite, chlorite, calcite, and quartz. Hydrocarbon stains between calcite and quartz and yellow flourescent, primary, hydrocarbon inclusions in quartz are indicative of migrations of hydrocarbon-bearing fluids during uplift from mid-crustal depth. Further uplift was associated with meteoric water infiltration along shear-zones as recorded by light d13C and d18O values, low trace element concentrations, all-liquid primary fluid inclusions and encased pollens and cuticules of terrestrial plants in a second fracture-calcite crystallised after quartz. A simultaneous meteoric influence in the overlying Pannonian (12.7-3 Ma) sediments is indicated by extensive plagioclase dissolution, calcite cement geochemistry and low-salinity, all-liquid fluid inclusions. The thermal subsidence of the basin led to isolation of the hydrologic system from the surface. Diminishing meteoric influence is recorded by increasing fluid inclusion salinities of secondary inclusions in calcite and quartz in the basement fractures and of primary inclusions hosted in late calcite and quartz in the sediments. A sudden decrease of the fluid inclusion salinities from 4.5 to 1 wt.% NaClcq. at ~ 130°C both in burial cements and fracture-filling minerals represents a newly established hydrological system, which redistributed the interstitial fluids, including hydrocarbons. This hydraulic inversion is indicated by abundant flourescent, secondary fluid inclusions in fracture-filling minerals. Finally, the Pliocene to recent tectonic inversion reopened fractures in the crystalline basement, and induced a rapid crystallisation of laumontite. These results support a long-standing (late Miocene to recent) hydraulic connection between fractured crystalline basement and overlying sediments in the central part of the Pannonian Basin. © 2002 Elsevier Science B.V. All rights reserved.

    Original languageEnglish
    Pages (from-to)91-120
    Number of pages30
    JournalChemical Geology
    Volume182
    Issue number2-4
    DOIs
    Publication statusPublished - 2002

    Fingerprint

    fluid inclusion
    calcite
    quartz
    fluid
    basin
    hydrocarbon
    sediment
    inversion tectonics
    uplift
    basin evolution
    meteoric water
    salinity
    shear zone
    cement
    subsidence
    laumontite
    hydraulics
    brittle fracture
    liquid
    kaolin

    Keywords

    • Fluid inclusions
    • Fracture diagenesis
    • Hungary
    • Meteoric diagenesis
    • Pannonian basin
    • Stable isotopes

    Cite this

    Juhász, Attila ; Tóth, Tivadar M. ; Ramseyer, Karl ; Matter, Albert. / Connected fluid evolution in fractured crystalline basement and overlying sediments, Pannonian Basin, SE Hungary. In: Chemical Geology. 2002 ; Vol. 182, No. 2-4. pp. 91-120.
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    abstract = "Uplifted crystalline basement highs have played an important role in the hydrologic history of the Pannonian Basin providing conduits for fluid migration during basin evolution. Petrographic, stable isotope, electron microprobe and fluid-inclusion studies support a five-step basin evolution; (1) formation of crystalline core-complexes, (2) percolation of meteoric water through shear zones, (3) basinwide thermal subsidence, (4) hydrologic inversion, and (5) tectonic inversion. Brittle fractures in the basement are the results of uplift during core complex formation and contain pyrite, kaolin, illite, chlorite, calcite, and quartz. Hydrocarbon stains between calcite and quartz and yellow flourescent, primary, hydrocarbon inclusions in quartz are indicative of migrations of hydrocarbon-bearing fluids during uplift from mid-crustal depth. Further uplift was associated with meteoric water infiltration along shear-zones as recorded by light d13C and d18O values, low trace element concentrations, all-liquid primary fluid inclusions and encased pollens and cuticules of terrestrial plants in a second fracture-calcite crystallised after quartz. A simultaneous meteoric influence in the overlying Pannonian (12.7-3 Ma) sediments is indicated by extensive plagioclase dissolution, calcite cement geochemistry and low-salinity, all-liquid fluid inclusions. The thermal subsidence of the basin led to isolation of the hydrologic system from the surface. Diminishing meteoric influence is recorded by increasing fluid inclusion salinities of secondary inclusions in calcite and quartz in the basement fractures and of primary inclusions hosted in late calcite and quartz in the sediments. A sudden decrease of the fluid inclusion salinities from 4.5 to 1 wt.{\%} NaClcq. at ~ 130°C both in burial cements and fracture-filling minerals represents a newly established hydrological system, which redistributed the interstitial fluids, including hydrocarbons. This hydraulic inversion is indicated by abundant flourescent, secondary fluid inclusions in fracture-filling minerals. Finally, the Pliocene to recent tectonic inversion reopened fractures in the crystalline basement, and induced a rapid crystallisation of laumontite. These results support a long-standing (late Miocene to recent) hydraulic connection between fractured crystalline basement and overlying sediments in the central part of the Pannonian Basin. {\circledC} 2002 Elsevier Science B.V. All rights reserved.",
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    Connected fluid evolution in fractured crystalline basement and overlying sediments, Pannonian Basin, SE Hungary. / Juhász, Attila; Tóth, Tivadar M.; Ramseyer, Karl; Matter, Albert.

    In: Chemical Geology, Vol. 182, No. 2-4, 2002, p. 91-120.

    Research output: Contribution to journalArticle

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    AU - Tóth, Tivadar M.

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    KW - Fracture diagenesis

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    KW - Meteoric diagenesis

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