Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

Kai Zhang; Bernd Tieke; Filipe Vilela; Peter J. Skabara

doi:10.1002/marc.201100045

Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

Kai Zhang, Bernd Tieke^*, Filipe Vilela, Peter J. Skabara

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)

Original language	English
Pages (from-to)	825-830
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	32
Issue number	11
DOIs	https://doi.org/10.1002/marc.201100045
Publication status	Published - 1 Jun 2011

Keywords

conjugated polymers
diketopyrrolopyrrole
DPP
microporous materials
networks
ORDERED MESOPOROUS MATERIALS
COVALENT ORGANIC FRAMEWORKS
HYDROGEN STORAGE MATERIALS
POLYMER SOLAR-CELLS
SURFACE-AREA
INTRINSIC MICROPOROSITY
HIGHLY LUMINESCENT
MAIN-CHAIN
ADSORPTION
BANDGAP

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10.1002/marc.201100045

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title = "Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole",

abstract = "pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)",

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author = "Kai Zhang and Bernd Tieke and Filipe Vilela and Skabara, {Peter J.}",

year = "2011",

month = jun,

day = "1",

doi = "10.1002/marc.201100045",

language = "English",

volume = "32",

pages = "825--830",

journal = "Macromolecular Rapid Communications",

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publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

AU - Zhang, Kai

AU - Tieke, Bernd

AU - Vilela, Filipe

AU - Skabara, Peter J.

PY - 2011/6/1

Y1 - 2011/6/1

N2 - pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)

AB - pi-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m(2) . g(-1)

KW - conjugated polymers

KW - diketopyrrolopyrrole

KW - DPP

KW - microporous materials

KW - networks

KW - ORDERED MESOPOROUS MATERIALS

KW - COVALENT ORGANIC FRAMEWORKS

KW - HYDROGEN STORAGE MATERIALS

KW - POLYMER SOLAR-CELLS

KW - SURFACE-AREA

KW - INTRINSIC MICROPOROSITY

KW - HIGHLY LUMINESCENT

KW - MAIN-CHAIN

KW - ADSORPTION

KW - BANDGAP

U2 - 10.1002/marc.201100045

DO - 10.1002/marc.201100045

M3 - Article

C2 - 21500301

SN - 1022-1336

VL - 32

SP - 825

EP - 830

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 11

ER -

Conjugated microporous networks on the basis of 2,3,5,6-tetraarylated diketopyrrolo[3,4-c]pyrrole

Abstract

Keywords

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