Complexes of sulphur bis(t-butylimide) with some transition metals

W. Edward Lindsell; Gavin R. Faulds

doi:10.1039/DT9750000040

Complexes of sulphur bis(t-butylimide) with some transition metals

W. Edward Lindsell
, Gavin R. Faulds

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)₄{S(NBu^t)₂}] (I; M = Cr, Mo, and W), [MCl₂{S(NBu^t)₂}₂] (II; M = Pd or Pt), and [PtCl₂{S(NBu^t)₂}(NH₂Bu ^t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., ¹H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.

Original language	English
Pages (from-to)	40-43
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	1
DOIs	https://doi.org/10.1039/DT9750000040
Publication status	Published - 1975

Access to Document

10.1039/DT9750000040

Cite this

@article{036184ff916c47c7a15f3a08a855cc45,

title = "Complexes of sulphur bis(t-butylimide) with some transition metals",

abstract = "The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4\{S(NBut)2\}] (I; M = Cr, Mo, and W), [MCl2\{S(NBut)2\}2] (II; M = Pd or Pt), and [PtCl2\{S(NBut)2\}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.",

author = "Lindsell, \{W. Edward\} and Faulds, \{Gavin R.\}",

year = "1975",

doi = "10.1039/DT9750000040",

language = "English",

pages = "40--43",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

number = "1",

}

TY - JOUR

T1 - Complexes of sulphur bis(t-butylimide) with some transition metals

AU - Lindsell, W. Edward

AU - Faulds, Gavin R.

PY - 1975

Y1 - 1975

N2 - The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}] (I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2] (II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.

AB - The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}] (I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2] (II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.

UR - https://www.scopus.com/pages/publications/37049123916

U2 - 10.1039/DT9750000040

DO - 10.1039/DT9750000040

M3 - Article

SN - 1472-7773

SP - 40

EP - 43

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 1

ER -

Complexes of sulphur bis(t-butylimide) with some transition metals

Abstract

Access to Document

Other files and links

Fingerprint

Cite this