Complexes of sulphur bis(t-butylimide) with some transition metals

W. Edward Lindsell, Gavin R. Faulds

Research output: Contribution to journalArticle

Abstract

The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}] (I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2] (II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.

Original languageEnglish
Pages (from-to)40-43
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
Issue number1
DOIs
Publication statusPublished - 1975

Fingerprint

Carbon Monoxide
Sulfur
Transition metals
Ligands

Cite this

@article{036184ff916c47c7a15f3a08a855cc45,
title = "Complexes of sulphur bis(t-butylimide) with some transition metals",
abstract = "The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}] (I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2] (II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.",
author = "Lindsell, {W. Edward} and Faulds, {Gavin R.}",
year = "1975",
doi = "10.1039/DT9750000040",
language = "English",
pages = "40--43",
journal = "Journal of the Chemical Society, Dalton Transactions",
issn = "1472-7773",
number = "1",

}

Complexes of sulphur bis(t-butylimide) with some transition metals. / Lindsell, W. Edward; Faulds, Gavin R.

In: Journal of the Chemical Society, Dalton Transactions, No. 1, 1975, p. 40-43.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Complexes of sulphur bis(t-butylimide) with some transition metals

AU - Lindsell, W. Edward

AU - Faulds, Gavin R.

PY - 1975

Y1 - 1975

N2 - The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}] (I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2] (II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.

AB - The preparation of complexes of transition metals with the new ligand sulphur bis(t-butylimide) is described. Complexes [M(CO)4{S(NBut)2}] (I; M = Cr, Mo, and W), [MCl2{S(NBut)2}2] (II; M = Pd or Pt), and [PtCl2{S(NBut)2}(NH2Bu t)], (III), have been characterised by analytical and spectroscopic methods. The i.r., 1H n.m.r., and mass spectra of the complexes are discussed and structures are assigned.

UR - http://www.scopus.com/inward/record.url?scp=37049123916&partnerID=8YFLogxK

U2 - 10.1039/DT9750000040

DO - 10.1039/DT9750000040

M3 - Article

SP - 40

EP - 43

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1472-7773

IS - 1

ER -