Complex Thermal Expansion Properties in a Molecular Honeycomb Lattice

Jonathan J. Loughrey; Tim P. Comyn; David C. Apperley; Marc A. Little; Malcolm A. Halcrow

doi:10.1039/c4cc02198c

Complex Thermal Expansion Properties in a Molecular Honeycomb Lattice

Jonathan J. Loughrey, Tim P. Comyn, David C. Apperley, Marc A. Little, Malcolm A. Halcrow^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

[FeL₃][BF₄]₂·xH₂O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150–240 K but positive thermal expansion at 240–300 K, linked to rearrangement of anions and water molecules within pores in the lattice.

Original language	English
Pages (from-to)	7601-7603
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	57
DOIs	https://doi.org/10.1039/c4cc02198c
Publication status	Published - 21 Jul 2014

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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@article{4c443129ce5b492683cff036c2720f35,

title = "Complex Thermal Expansion Properties in a Molecular Honeycomb Lattice",

abstract = "[FeL3][BF4]2·xH2O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150–240 K but positive thermal expansion at 240–300 K, linked to rearrangement of anions and water molecules within pores in the lattice.",

author = "Loughrey, {Jonathan J.} and Comyn, {Tim P.} and Apperley, {David C.} and Little, {Marc A.} and Halcrow, {Malcolm A.}",

year = "2014",

month = jul,

day = "21",

doi = "10.1039/c4cc02198c",

language = "English",

volume = "50",

pages = "7601--7603",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "57",

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TY - JOUR

T1 - Complex Thermal Expansion Properties in a Molecular Honeycomb Lattice

AU - Loughrey, Jonathan J.

AU - Comyn, Tim P.

AU - Apperley, David C.

AU - Little, Marc A.

AU - Halcrow, Malcolm A.

PY - 2014/7/21

Y1 - 2014/7/21

N2 - [FeL3][BF4]2·xH2O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150–240 K but positive thermal expansion at 240–300 K, linked to rearrangement of anions and water molecules within pores in the lattice.

AB - [FeL3][BF4]2·xH2O (L = 3-(pyrazinyl)-1H-pyrazole) shows negative thermal expansion between 150–240 K but positive thermal expansion at 240–300 K, linked to rearrangement of anions and water molecules within pores in the lattice.

UR - http://www.scopus.com/inward/record.url?scp=84903143345&partnerID=8YFLogxK

U2 - 10.1039/c4cc02198c

DO - 10.1039/c4cc02198c

M3 - Article

AN - SCOPUS:84903143345

SN - 1359-7345

VL - 50

SP - 7601

EP - 7603

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Complex Thermal Expansion Properties in a Molecular Honeycomb Lattice

Abstract

ASJC Scopus subject areas

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