Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer

Ross McLellan; Stephanie M Taylor; Ruaraidh D McIntosh; Euan K Brechin; Scott J Dalgarno

doi:10.1039/c3dt50294e

Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic Mn^IVMn^III dimer

Ross McLellan
, Stephanie M Taylor
, Ruaraidh D McIntosh
, Euan K Brechin
, Scott J Dalgarno

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH(2)) have been utilised in the facile synthesis of a (MnMnIV)-Mn-III dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

Original language	English
Pages (from-to)	6697-6700
Number of pages	4
Journal	Dalton Transactions
Volume	42
Issue number	19
DOIs	https://doi.org/10.1039/c3dt50294e
Publication status	Published - 2013

Keywords

SINGLE-MOLECULE MAGNETS
CLUSTERS
COMPLEXES
FAMILY

Access to Document

10.1039/c3dt50294e

Cite this

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title = "Complementary ligands direct the formation of a calix[8]arene-supported ferromagnetic MnIVMnIII dimer",

abstract = "A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH(2)) have been utilised in the facile synthesis of a (MnMnIV)-Mn-III dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.",

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AU - McLellan, Ross

AU - Taylor, Stephanie M

AU - McIntosh, Ruaraidh D

AU - Brechin, Euan K

AU - Dalgarno, Scott J

PY - 2013

Y1 - 2013

N2 - A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH(2)) have been utilised in the facile synthesis of a (MnMnIV)-Mn-III dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

AB - A combination of complementary ligands, p-tert-butylcalix[8]arene (TBC[8]) and phenyl salicylaldoxime (Ph-saoH(2)) have been utilised in the facile synthesis of a (MnMnIV)-Mn-III dimer. Magnetic measurements reveal ferromagnetic exchange between the two metal ions.

KW - SINGLE-MOLECULE MAGNETS

KW - CLUSTERS

KW - COMPLEXES

KW - FAMILY

U2 - 10.1039/c3dt50294e

DO - 10.1039/c3dt50294e

M3 - Article

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SN - 1477-9226

VL - 42

SP - 6697

EP - 6700

JO - Dalton Transactions

JF - Dalton Transactions

IS - 19