Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel

Sergio Sanz; Jamie M. Frost; Thayalan Rajeshkumar; Scott J. Dalgarno; Gopalan Rajaraman; Wolfgang Wernsdorfer; Juergen Schnack; Paul. J. Lusby; Euan K. Brechin

doi:10.1002/chem.201304740

Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel

Sergio Sanz, Jamie M. Frost, Thayalan Rajeshkumar, Scott J. Dalgarno, Gopalan Rajaraman^*, Wolfgang Wernsdorfer, Juergen Schnack, Paul. J. Lusby, Euan K. Brechin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.

Original language	English
Pages (from-to)	3010-3013
Number of pages	4
Journal	Chemistry - A European Journal
Volume	20
Issue number	11
DOIs	https://doi.org/10.1002/chem.201304740
Publication status	Published - 10 Mar 2014

Keywords

density functional calculations
finite-temperature Lanczos method
manganese
molecular magnets
self-assembly
SINGLE-MOLECULE MAGNETS
SPIN GROUND-STATE
LANCZOS METHOD
LOOP STRUCTURE
MIXED-VALENT
SHAPED MN-12
SOLID-STATE
COMPLEXES
MANGANESE
SYSTEMS

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title = "Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel",

abstract = "Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.",

keywords = "density functional calculations, finite-temperature Lanczos method, manganese, molecular magnets, self-assembly, SINGLE-MOLECULE MAGNETS, SPIN GROUND-STATE, LANCZOS METHOD, LOOP STRUCTURE, MIXED-VALENT, SHAPED MN-12, SOLID-STATE, COMPLEXES, MANGANESE, SYSTEMS",

author = "Sergio Sanz and Frost, {Jamie M.} and Thayalan Rajeshkumar and Dalgarno, {Scott J.} and Gopalan Rajaraman and Wolfgang Wernsdorfer and Juergen Schnack and Lusby, {Paul. J.} and Brechin, {Euan K.}",

year = "2014",

month = mar,

day = "10",

doi = "10.1002/chem.201304740",

language = "English",

volume = "20",

pages = "3010--3013",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

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T1 - Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel

AU - Sanz, Sergio

AU - Frost, Jamie M.

AU - Rajeshkumar, Thayalan

AU - Dalgarno, Scott J.

AU - Rajaraman, Gopalan

AU - Wernsdorfer, Wolfgang

AU - Schnack, Juergen

AU - Lusby, Paul. J.

AU - Brechin, Euan K.

PY - 2014/3/10

Y1 - 2014/3/10

N2 - Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.

AB - Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.

KW - density functional calculations

KW - finite-temperature Lanczos method

KW - manganese

KW - molecular magnets

KW - self-assembly

KW - SINGLE-MOLECULE MAGNETS

KW - SPIN GROUND-STATE

KW - LANCZOS METHOD

KW - LOOP STRUCTURE

KW - MIXED-VALENT

KW - SHAPED MN-12

KW - SOLID-STATE

KW - COMPLEXES

KW - MANGANESE

KW - SYSTEMS

U2 - 10.1002/chem.201304740

DO - 10.1002/chem.201304740

M3 - Article

C2 - 24470126

SN - 0947-6539

VL - 20

SP - 3010

EP - 3013

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 11

ER -

Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel

Abstract

Keywords

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