Combining Complementary Ligands into one Framework for the Construction of a Ferromagnetically Coupled [Mn-12(III)] Wheel

Sergio Sanz, Jamie M. Frost, Thayalan Rajeshkumar, Scott J. Dalgarno, Gopalan Rajaraman, Wolfgang Wernsdorfer, Juergen Schnack, Paul. J. Lusby, Euan K. Brechin

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17 Citations (Scopus)

Abstract

Phenolic oxime and diethanolamine moieties have been combined into one organic framework, resulting in the formation of a novel ligand type that can be employed to construct a rare and unusual dodecametallic Mn wheel, within which nearest neighbours are coupled ferromagnetically.

Original languageEnglish
Pages (from-to)3010-3013
Number of pages4
JournalChemistry - A European Journal
Volume20
Issue number11
DOIs
Publication statusPublished - 10 Mar 2014

Keywords

  • density functional calculations
  • finite-temperature Lanczos method
  • manganese
  • molecular magnets
  • self-assembly
  • SINGLE-MOLECULE MAGNETS
  • SPIN GROUND-STATE
  • LANCZOS METHOD
  • LOOP STRUCTURE
  • MIXED-VALENT
  • SHAPED MN-12
  • SOLID-STATE
  • COMPLEXES
  • MANGANESE
  • SYSTEMS

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