Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF3C2CF3)2(η5-C5H5)] and [Mo(C4F6)2(C5H5)2]

Jack L. Davidson; Michael Green; David W. A. Sharp; F. Gordon A. Stone; Alan J. Welch

doi:10.1039/C3974000706b

Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF₃C₂CF₃)₂(η⁵-C₅H₅)] and [Mo(C₄F₆)₂(C₅H₅)₂]

Jack L. Davidson
, Michael Green
, David W. A. Sharp^*
, F. Gordon A. Stone
, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

Reaction of [MCl(CO)₃(η⁵-C₅H ₅)] (M = Mo or W) with acetylenes affords the 16-electron species [MCl-(RC₂R)₂(η⁵-C₅H ₅)]; structurally characterised by X-ray crystallography, and shown to react with donor ligands and with TlC₅H₅.

Original language	English
Pages (from-to)	706-708
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/C3974000706b
Publication status	Published - 1974

ASJC Scopus subject areas

Molecular Medicine

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@article{d360d9996cbf486c90f466b2627d4a77,

title = "Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF3C2CF3)2(η5-C5H5)] and [Mo(C4F6)2(C5H5)2]",

abstract = "Reaction of [MCl(CO)3(η5-C5H 5)] (M = Mo or W) with acetylenes affords the 16-electron species [MCl-(RC2R)2(η5-C5H 5)]; structurally characterised by X-ray crystallography, and shown to react with donor ligands and with TlC5H5.",

author = "Davidson, \{Jack L.\} and Michael Green and Sharp, \{David W. A.\} and Stone, \{F. Gordon A.\} and Welch, \{Alan J.\}",

year = "1974",

doi = "10.1039/C3974000706b",

language = "English",

pages = "706--708",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "17",

}

Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF₃C₂CF₃)₂(η⁵-C₅H₅)] and [Mo(C₄F₆)₂(C₅H₅)₂]. / Davidson, Jack L.; Green, Michael; Sharp, David W. A. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 17, 1974, p. 706-708.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF3C2CF3)2(η5-C5H5)] and [Mo(C4F6)2(C5H5)2]

AU - Davidson, Jack L.

AU - Green, Michael

AU - Sharp, David W. A.

AU - Stone, F. Gordon A.

AU - Welch, Alan J.

PY - 1974

Y1 - 1974

N2 - Reaction of [MCl(CO)3(η5-C5H 5)] (M = Mo or W) with acetylenes affords the 16-electron species [MCl-(RC2R)2(η5-C5H 5)]; structurally characterised by X-ray crystallography, and shown to react with donor ligands and with TlC5H5.

AB - Reaction of [MCl(CO)3(η5-C5H 5)] (M = Mo or W) with acetylenes affords the 16-electron species [MCl-(RC2R)2(η5-C5H 5)]; structurally characterised by X-ray crystallography, and shown to react with donor ligands and with TlC5H5.

UR - https://www.scopus.com/pages/publications/37049115064

U2 - 10.1039/C3974000706b

DO - 10.1039/C3974000706b

M3 - Article

SN - 0022-4936

SP - 706

EP - 708

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF₃C₂CF₃)₂(η⁵-C₅H₅)] and [Mo(C₄F₆)₂(C₅H₅)₂]

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