Co-ordinatively unsaturated molybdenum and tungsten cyclopentadienyl complexes; molecular structures of [WCl(CF3C2CF3)25-C5H5)] and [Mo(C4F6)2(C5H5)2]

Jack L. Davidson, Michael Green, David W. A. Sharp, F. Gordon A. Stone, Alan J. Welch

Research output: Contribution to journalArticle

Abstract

Reaction of [MCl(CO)35-C5H 5)] (M = Mo or W) with acetylenes affords the 16-electron species [MCl-(RC2R)25-C5H 5)]; structurally characterised by X-ray crystallography, and shown to react with donor ligands and with TlC5H5.

Original languageEnglish
Pages (from-to)706-708
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
Publication statusPublished - 1974

ASJC Scopus subject areas

  • Molecular Medicine

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