Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η5-C5H 5){C(CF3) = C(CF3)C(CF3) = C(CF 3)}(CO)2Co(CO)2]

Jack L. Davidson; Ljubica Manojlovic-Muir; Kenneth W. Muir; Alison N. Keith

Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]

Jack L. Davidson, Ljubica Manojlovic-Muir, Kenneth W. Muir, Alison N. Keith

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

Bis(hexafluorobut-2-yne) complexes [M(?⁵-C₅H ₅)-Cl(CF₃C=CCF₃)₂] (M = Mo, W) react with [Co₂(CO)₈] to give acetylene-bridged derivatives [M(?⁵-C₅H₅)CO(µ-CF ₃C=CCF₃)₂Co(CO)₂] which react further to give the metallacyclopentadiene complexes [M(?⁵-C ₅H₅) {C(CF₃)=C(CF₃)C(CF ₃)C(CF₃) }(CO)₂Co(CO)₂] which, for M = W, has been structurally characterised by X-ray diffraction methods.

Original language	English
Pages (from-to)	749-750
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
Publication status	Published - 1980

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Davidson, J. L., Manojlovic-Muir, L., Muir, K. W., & Keith, A. N. (1980). Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]. Journal of the Chemical Society, Chemical Communications, (16), 749-750.

Davidson, Jack L. ; Manojlovic-Muir, Ljubica ; Muir, Kenneth W. et al. / Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]. In: Journal of the Chemical Society, Chemical Communications. 1980 ; No. 16. pp. 749-750.

@article{ca35cf5631544e188037f3514cbf3831,

title = "Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η5-C5H 5){C(CF3) = C(CF3)C(CF3) = C(CF 3)}(CO)2Co(CO)2]",

abstract = "Bis(hexafluorobut-2-yne) complexes [M(?5-C5H 5)-Cl(CF3C=CCF3)2] (M = Mo, W) react with [Co2(CO)8] to give acetylene-bridged derivatives [M(?5-C5H5)CO(µ-CF 3C=CCF3)2Co(CO)2] which react further to give the metallacyclopentadiene complexes [M(?5-C 5H5) {C(CF3)=C(CF3)C(CF 3)C(CF3) }(CO)2Co(CO)2] which, for M = W, has been structurally characterised by X-ray diffraction methods.",

author = "Davidson, {Jack L.} and Ljubica Manojlovic-Muir and Muir, {Kenneth W.} and Keith, {Alison N.}",

year = "1980",

language = "English",

pages = "749--750",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "16",

}

Davidson, JL, Manojlovic-Muir, L, Muir, KW & Keith, AN 1980, 'Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]', Journal of the Chemical Society, Chemical Communications, no. 16, pp. 749-750.

Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]. / Davidson, Jack L.; Manojlovic-Muir, Ljubica; Muir, Kenneth W. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 16, 1980, p. 749-750.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η5-C5H 5){C(CF3) = C(CF3)C(CF3) = C(CF 3)}(CO)2Co(CO)2]

AU - Davidson, Jack L.

AU - Manojlovic-Muir, Ljubica

AU - Muir, Kenneth W.

AU - Keith, Alison N.

PY - 1980

Y1 - 1980

N2 - Bis(hexafluorobut-2-yne) complexes [M(?5-C5H 5)-Cl(CF3C=CCF3)2] (M = Mo, W) react with [Co2(CO)8] to give acetylene-bridged derivatives [M(?5-C5H5)CO(µ-CF 3C=CCF3)2Co(CO)2] which react further to give the metallacyclopentadiene complexes [M(?5-C 5H5) {C(CF3)=C(CF3)C(CF 3)C(CF3) }(CO)2Co(CO)2] which, for M = W, has been structurally characterised by X-ray diffraction methods.

AB - Bis(hexafluorobut-2-yne) complexes [M(?5-C5H 5)-Cl(CF3C=CCF3)2] (M = Mo, W) react with [Co2(CO)8] to give acetylene-bridged derivatives [M(?5-C5H5)CO(µ-CF 3C=CCF3)2Co(CO)2] which react further to give the metallacyclopentadiene complexes [M(?5-C 5H5) {C(CF3)=C(CF3)C(CF 3)C(CF3) }(CO)2Co(CO)2] which, for M = W, has been structurally characterised by X-ray diffraction methods.

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M3 - Article

SN - 0022-4936

SP - 749

EP - 750

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Davidson JL, Manojlovic-Muir L, Muir KW, Keith AN. Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]. Journal of the Chemical Society, Chemical Communications. 1980;(16):749-750.

Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η5-C5H 5){C(CF3) = C(CF3)C(CF3) = C(CF 3)}(CO)2Co(CO)2]

Abstract

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Co-ordinatively unsaturated acetylene complexes of molybdenum and tungsten; the influence of a second metal on the cyclisation of co-ordinated acetylenes. X-ray crystal structure of [W(η⁵-C₅H ₅){C(CF₃) = C(CF₃)C(CF₃) = C(CF ₃)}(CO)₂Co(CO)₂]