closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes:  The Molecular Structures of [6,6-(Et3P)2-1,2,6-C2CoB7H9] and [1,1-(Et3P)2-1,2,4-C2CoB8H10]

Geoffrey K. Barker; Maria P. Garcia; Michael Green; Geoffrey N. Pain; F. Gordon A. Stone; Stuart K. R. Jones; Alan J. Welch

doi:10.1039/C39810000652

closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes: The Molecular Structures of [6,6-(Et₃P)₂-1,2,6-C₂CoB₇H₉] and [1,1-(Et₃P)₂-1,2,4-C₂CoB₈H₁₀]

Geoffrey K. Barker^*, Maria P. Garcia, Michael Green, Geoffrey N. Pain, F. Gordon A. Stone, Stuart K. R. Jones, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

Reaction of [Co(PEt₃)₄] with nido-4,5-C ₂B₇H₁₁ and nido-5,6-C₂B ₈H₁₂ affords the wine-red compound closo-[6,6-(Et ₃P)₂-1,2,6-C₂CoB₇H₉] and the purple compound closo-[1,1-(Et₃P)₂-1,2,4-CoC ₂B₈H₁₀], respectively, both products being structurally characterised by single-crystal X-ray diffraction studies.

Original language	English
Pages (from-to)	652-653
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39810000652
Publication status	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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Barker, G. K., Garcia, M. P., Green, M., Pain, G. N., Stone, F. G. A., Jones, S. K. R., & Welch, A. J. (1981). closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes: The Molecular Structures of [6,6-(Et₃P)₂-1,2,6-C₂CoB₇H₉] and [1,1-(Et₃P)₂-1,2,4-C₂CoB₈H₁₀]. Journal of the Chemical Society, Chemical Communications, (13), 652-653. https://doi.org/10.1039/C39810000652

@article{4d75cab11b0140e48af665fdd582cff2,

title = "closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes: The Molecular Structures of [6,6-(Et3P)2-1,2,6-C2CoB7H9] and [1,1-(Et3P)2-1,2,4-C2CoB8H10]",

abstract = "Reaction of [Co(PEt3)4] with nido-4,5-C 2B7H11 and nido-5,6-C2B 8H12 affords the wine-red compound closo-[6,6-(Et 3P)2-1,2,6-C2CoB7H9] and the purple compound closo-[1,1-(Et3P)2-1,2,4-CoC 2B8H10], respectively, both products being structurally characterised by single-crystal X-ray diffraction studies.",

author = "Barker, {Geoffrey K.} and Garcia, {Maria P.} and Michael Green and Pain, {Geoffrey N.} and Stone, {F. Gordon A.} and Jones, {Stuart K. R.} and Welch, {Alan J.}",

year = "1981",

doi = "10.1039/C39810000652",

language = "English",

pages = "652--653",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "13",

}

closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes: The Molecular Structures of [6,6-(Et₃P)₂-1,2,6-C₂CoB₇H₉] and [1,1-(Et₃P)₂-1,2,4-C₂CoB₈H₁₀]. / Barker, Geoffrey K.; Garcia, Maria P.; Green, Michael et al.
In: Journal of the Chemical Society, Chemical Communications, No. 13, 1981, p. 652-653.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes: The Molecular Structures of [6,6-(Et3P)2-1,2,6-C2CoB7H9] and [1,1-(Et3P)2-1,2,4-C2CoB8H10]

AU - Barker, Geoffrey K.

AU - Garcia, Maria P.

AU - Green, Michael

AU - Pain, Geoffrey N.

AU - Stone, F. Gordon A.

AU - Jones, Stuart K. R.

AU - Welch, Alan J.

PY - 1981

Y1 - 1981

N2 - Reaction of [Co(PEt3)4] with nido-4,5-C 2B7H11 and nido-5,6-C2B 8H12 affords the wine-red compound closo-[6,6-(Et 3P)2-1,2,6-C2CoB7H9] and the purple compound closo-[1,1-(Et3P)2-1,2,4-CoC 2B8H10], respectively, both products being structurally characterised by single-crystal X-ray diffraction studies.

AB - Reaction of [Co(PEt3)4] with nido-4,5-C 2B7H11 and nido-5,6-C2B 8H12 affords the wine-red compound closo-[6,6-(Et 3P)2-1,2,6-C2CoB7H9] and the purple compound closo-[1,1-(Et3P)2-1,2,4-CoC 2B8H10], respectively, both products being structurally characterised by single-crystal X-ray diffraction studies.

UR - http://www.scopus.com/inward/record.url?scp=37049097831&partnerID=8YFLogxK

U2 - 10.1039/C39810000652

DO - 10.1039/C39810000652

M3 - Article

SN - 0022-4936

SP - 652

EP - 653

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 13

ER -

closo-Carbametallaboranes from Direct Insertion into nido-Carbaboranes: The Molecular Structures of [6,6-(Et₃P)₂-1,2,6-C₂CoB₇H₉] and [1,1-(Et₃P)₂-1,2,4-C₂CoB₈H₁₀]

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