Chromium-containing organometallic self-organized materials for nanophotonics

Larisa G. Klapshina; Ilya S. Grigoryev; Vladimir V. Semenov; William E. Douglas; Boris A. Bushuk; Sergei B. Bushuk; Andrey Yu Lukianov; Andrey V. Afanasev; Robert E. Benfield; Henry T. Bookey; Ajoy K. Kar; Ildus F. Nurgaleev; Alexey I. Korytin; Alexander M. Sergeev

doi:10.1109/NO.2006.348368

Chromium-containing organometallic self-organized materials for nanophotonics

Larisa G. Klapshina
, Ilya S. Grigoryev
, Vladimir V. Semenov
, William E. Douglas
, Boris A. Bushuk
, Sergei B. Bushuk
, Andrey Yu Lukianov
, Andrey V. Afanasev
, Robert E. Benfield
, Henry T. Bookey
, Ajoy K. Kar
, Ildus F. Nurgaleev
, Alexey I. Korytin
, Alexander M. Sergeev

School of Engineering & Physical Sciences

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

2 Citations (Scopus)

Abstract

Novel non-linear optical polymeric film-producing nanocomposites based on bis(arene)chromium complexes incorporated into CN-containing matrices have been developed. Measurements by the spectrally resolved two-beam coupling method with a femtosecond range of pulse widths (central wavelength 795-800 nm) confirmed that the test composites exhibited a significant cubic nonlinear optical susceptibility of the ultra-fast electronic type. An open aperture Z-scan of the polymer film at 1550 nm showed a value of 9 x 10^-19 cm³ W^-2 for the three-photon absorption coefficient. The electro-optical measurements of the polymer composite showed a high electro-optical response (r₃₃.n³ = 4.245 pm V^-1 at modulation frequency 210 Hz and poling DC voltage 2.16 V). A significant enhancement of the signals with a decrease in modulation frequency was observed consistent with an essential contribution of orientation effects to the electro-optical response. The measurements in the absence of external electrical fields showed a natural anisotropy resulting from self-organization taking place during the film formation process as confirmed by electron diffraction studies. A single Cr-C distance was found in the EXAFS data refinement, showing that the arene rings are parallel and symmetric as in bis(benzene)chromium. ©2006 IEEE.

Original language	English
Title of host publication	2006 Northern Optics Conference, NO
Pages	29-34
Number of pages	6
DOIs	https://doi.org/10.1109/NO.2006.348368
Publication status	Published - 2006
Event	2006 Northern Optics Conference - Bergen, Norway Duration: 14 Jun 2006 → 16 Jun 2006

Conference

Conference	2006 Northern Optics Conference
Abbreviated title	NO
Country/Territory	Norway
City	Bergen
Period	14/06/06 → 16/06/06

Keywords

Chromium
CN-containing polymer
Cubic optical nonlinearity
Electro-optical coefficient

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10.1109/NO.2006.348368

Cite this

Klapshina, L. G., Grigoryev, I. S., Semenov, V. V., Douglas, W. E., Bushuk, B. A., Bushuk, S. B., Lukianov, A. Y., Afanasev, A. V., Benfield, R. E., Bookey, H. T., Kar, A. K., Nurgaleev, I. F., Korytin, A. I., & Sergeev, A. M. (2006). Chromium-containing organometallic self-organized materials for nanophotonics. In 2006 Northern Optics Conference, NO (pp. 29-34) https://doi.org/10.1109/NO.2006.348368

@inproceedings{0b5815c095a342bab44871d39142e124,

title = "Chromium-containing organometallic self-organized materials for nanophotonics",

abstract = "Novel non-linear optical polymeric film-producing nanocomposites based on bis(arene)chromium complexes incorporated into CN-containing matrices have been developed. Measurements by the spectrally resolved two-beam coupling method with a femtosecond range of pulse widths (central wavelength 795-800 nm) confirmed that the test composites exhibited a significant cubic nonlinear optical susceptibility of the ultra-fast electronic type. An open aperture Z-scan of the polymer film at 1550 nm showed a value of 9 x 10-19 cm3 W-2 for the three-photon absorption coefficient. The electro-optical measurements of the polymer composite showed a high electro-optical response (r33.n3 = 4.245 pm V-1 at modulation frequency 210 Hz and poling DC voltage 2.16 V). A significant enhancement of the signals with a decrease in modulation frequency was observed consistent with an essential contribution of orientation effects to the electro-optical response. The measurements in the absence of external electrical fields showed a natural anisotropy resulting from self-organization taking place during the film formation process as confirmed by electron diffraction studies. A single Cr-C distance was found in the EXAFS data refinement, showing that the arene rings are parallel and symmetric as in bis(benzene)chromium. {\textcopyright}2006 IEEE.",

keywords = "Chromium, CN-containing polymer, Cubic optical nonlinearity, Electro-optical coefficient",

author = "Klapshina, \{Larisa G.\} and Grigoryev, \{Ilya S.\} and Semenov, \{Vladimir V.\} and Douglas, \{William E.\} and Bushuk, \{Boris A.\} and Bushuk, \{Sergei B.\} and Lukianov, \{Andrey Yu\} and Afanasev, \{Andrey V.\} and Benfield, \{Robert E.\} and Bookey, \{Henry T.\} and Kar, \{Ajoy K.\} and Nurgaleev, \{Ildus F.\} and Korytin, \{Alexey I.\} and Sergeev, \{Alexander M.\}",

year = "2006",

doi = "10.1109/NO.2006.348368",

language = "English",

isbn = "1424404355",

pages = "29--34",

booktitle = "2006 Northern Optics Conference, NO",

note = "2006 Northern Optics Conference, NO ; Conference date: 14-06-2006 Through 16-06-2006",

}

Klapshina, LG, Grigoryev, IS, Semenov, VV, Douglas, WE, Bushuk, BA, Bushuk, SB, Lukianov, AY, Afanasev, AV, Benfield, RE, Bookey, HT, Kar, AK, Nurgaleev, IF, Korytin, AI & Sergeev, AM 2006, Chromium-containing organometallic self-organized materials for nanophotonics. in 2006 Northern Optics Conference, NO. pp. 29-34, 2006 Northern Optics Conference, Bergen, Norway, 14/06/06. https://doi.org/10.1109/NO.2006.348368

TY - GEN

T1 - Chromium-containing organometallic self-organized materials for nanophotonics

AU - Klapshina, Larisa G.

AU - Grigoryev, Ilya S.

AU - Semenov, Vladimir V.

AU - Douglas, William E.

AU - Bushuk, Boris A.

AU - Bushuk, Sergei B.

AU - Lukianov, Andrey Yu

AU - Afanasev, Andrey V.

AU - Benfield, Robert E.

AU - Bookey, Henry T.

AU - Kar, Ajoy K.

AU - Nurgaleev, Ildus F.

AU - Korytin, Alexey I.

AU - Sergeev, Alexander M.

PY - 2006

Y1 - 2006

N2 - Novel non-linear optical polymeric film-producing nanocomposites based on bis(arene)chromium complexes incorporated into CN-containing matrices have been developed. Measurements by the spectrally resolved two-beam coupling method with a femtosecond range of pulse widths (central wavelength 795-800 nm) confirmed that the test composites exhibited a significant cubic nonlinear optical susceptibility of the ultra-fast electronic type. An open aperture Z-scan of the polymer film at 1550 nm showed a value of 9 x 10-19 cm3 W-2 for the three-photon absorption coefficient. The electro-optical measurements of the polymer composite showed a high electro-optical response (r33.n3 = 4.245 pm V-1 at modulation frequency 210 Hz and poling DC voltage 2.16 V). A significant enhancement of the signals with a decrease in modulation frequency was observed consistent with an essential contribution of orientation effects to the electro-optical response. The measurements in the absence of external electrical fields showed a natural anisotropy resulting from self-organization taking place during the film formation process as confirmed by electron diffraction studies. A single Cr-C distance was found in the EXAFS data refinement, showing that the arene rings are parallel and symmetric as in bis(benzene)chromium. ©2006 IEEE.

AB - Novel non-linear optical polymeric film-producing nanocomposites based on bis(arene)chromium complexes incorporated into CN-containing matrices have been developed. Measurements by the spectrally resolved two-beam coupling method with a femtosecond range of pulse widths (central wavelength 795-800 nm) confirmed that the test composites exhibited a significant cubic nonlinear optical susceptibility of the ultra-fast electronic type. An open aperture Z-scan of the polymer film at 1550 nm showed a value of 9 x 10-19 cm3 W-2 for the three-photon absorption coefficient. The electro-optical measurements of the polymer composite showed a high electro-optical response (r33.n3 = 4.245 pm V-1 at modulation frequency 210 Hz and poling DC voltage 2.16 V). A significant enhancement of the signals with a decrease in modulation frequency was observed consistent with an essential contribution of orientation effects to the electro-optical response. The measurements in the absence of external electrical fields showed a natural anisotropy resulting from self-organization taking place during the film formation process as confirmed by electron diffraction studies. A single Cr-C distance was found in the EXAFS data refinement, showing that the arene rings are parallel and symmetric as in bis(benzene)chromium. ©2006 IEEE.

KW - Chromium

KW - CN-containing polymer

KW - Cubic optical nonlinearity

KW - Electro-optical coefficient

U2 - 10.1109/NO.2006.348368

DO - 10.1109/NO.2006.348368

M3 - Conference contribution

SN - 1424404355

SN - 9781424404353

SP - 29

EP - 34

BT - 2006 Northern Optics Conference, NO

T2 - 2006 Northern Optics Conference

Y2 - 14 June 2006 through 16 June 2006

ER -

Chromium-containing organometallic self-organized materials for nanophotonics

Abstract

Conference

Keywords

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