Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Guang Han; Srinivasa Popuri; Heather F. Greer; Lourdes F. Llin; Jan-Willem G Bos; Wuzong Z. Zhou; Douglas J. Paul; Hervé Ménard; Andrew R. Knox; Andrea Montecucco; Jonathan Siviter; Elena A. Man; Wen Guang Li; Manosh C. Paul; Min Gao; Tracy Sweet; Robert Freer; Feridoon Azough; Hasan Baig; Tapas K. Mallick; Duncan H. Gregory

doi:10.1002/aenm.201602328

Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Guang Han
, Srinivasa Popuri
, Heather F. Greer
, Lourdes F. Llin
, Jan-Willem G Bos
, Wuzong Z. Zhou
, Douglas J. Paul
, Hervé Ménard
, Andrew R. Knox
, Andrea Montecucco
, Jonathan Siviter
, Elena A. Man
, Wen Guang Li
, Manosh C. Paul
, Min Gao
, Tracy Sweet
, Robert Freer
, Feridoon Azough
, Hasan Baig
, Tapas K. Mallick

Duncan H. Gregory

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

147 Downloads (Pure)

Abstract

An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

Original language	English
Article number	1602328
Number of pages	7
Journal	Advanced Energy Materials
Volume	7
Issue number	13
Early online date	20 Feb 2017
DOIs	https://doi.org/10.1002/aenm.201602328
Publication status	Published - 5 Jul 2017

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This is the peer reviewed version of the following article: G. Han, S. R. Popuri, H. F. Greer, L. F. Llin, J.-W. G. Bos, W. Z. Zhou, D. J. Paul, H. Ménard, A. R. Knox, A. Montecucco, J. Siviter, E. A. Man, W.-g. Li, M. C. Paul, M. Gao, T. Sweet, R. Freer, F. Azough, H. Baig, T. K. Mallick, D. H. Gregory, Adv. Energy Mater. 2017, 1602328, which has been published in final form at http://dx.doi.org/10.1002/aenm.201602328. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
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Han, G., Popuri, S., Greer, H. F., Llin, L. F., Bos, J.-W. G., Zhou, W. Z., Paul, D. J., Ménard, H., Knox, A. R., Montecucco, A., Siviter, J., Man, E. A., Li, W. G., Paul, M. C., Gao, M., Sweet, T., Freer, R., Azough, F., Baig, H., ... Gregory, D. H. (2017). Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials. Advanced Energy Materials, 7(13), Article 1602328. https://doi.org/10.1002/aenm.201602328

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title = "Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials",

abstract = "An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.",

author = "Guang Han and Srinivasa Popuri and Greer, \{Heather F.\} and Llin, \{Lourdes F.\} and Bos, \{Jan-Willem G\} and Zhou, \{Wuzong Z.\} and Paul, \{Douglas J.\} and Herv{\'e} M{\'e}nard and Knox, \{Andrew R.\} and Andrea Montecucco and Jonathan Siviter and Man, \{Elena A.\} and Li, \{Wen Guang\} and Paul, \{Manosh C.\} and Min Gao and Tracy Sweet and Robert Freer and Feridoon Azough and Hasan Baig and Mallick, \{Tapas K.\} and Gregory, \{Duncan H.\}",

year = "2017",

month = jul,

day = "5",

doi = "10.1002/aenm.201602328",

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Han, G, Popuri, S, Greer, HF, Llin, LF, Bos, J-WG, Zhou, WZ, Paul, DJ, Ménard, H, Knox, AR, Montecucco, A, Siviter, J, Man, EA, Li, WG, Paul, MC, Gao, M, Sweet, T, Freer, R, Azough, F, Baig, H, Mallick, TK & Gregory, DH 2017, 'Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials', Advanced Energy Materials, vol. 7, no. 13, 1602328. https://doi.org/10.1002/aenm.201602328

TY - JOUR

T1 - Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

AU - Han, Guang

AU - Popuri, Srinivasa

AU - Greer, Heather F.

AU - Llin, Lourdes F.

AU - Bos, Jan-Willem G

AU - Zhou, Wuzong Z.

AU - Paul, Douglas J.

AU - Ménard, Hervé

AU - Knox, Andrew R.

AU - Montecucco, Andrea

AU - Siviter, Jonathan

AU - Man, Elena A.

AU - Li, Wen Guang

AU - Paul, Manosh C.

AU - Gao, Min

AU - Sweet, Tracy

AU - Freer, Robert

AU - Azough, Feridoon

AU - Baig, Hasan

AU - Mallick, Tapas K.

AU - Gregory, Duncan H.

PY - 2017/7/5

Y1 - 2017/7/5

N2 - An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

AB - An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

U2 - 10.1002/aenm.201602328

DO - 10.1002/aenm.201602328

M3 - Article

SN - 1614-6832

VL - 7

JO - Advanced Energy Materials

JF - Advanced Energy Materials

IS - 13

M1 - 1602328

ER -

Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

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