Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Guang Han; Srinivasa Popuri; Heather F. Greer; Lourdes F. Llin; Jan-Willem G Bos; Wuzong Z. Zhou; Douglas J. Paul; Hervé Ménard; Andrew R. Knox; Andrea Montecucco; Jonathan Siviter; Elena A. Man; Wen Guang Li; Manosh C. Paul; Min Gao; Tracy Sweet; Robert Freer; Feridoon Azough; Hasan Baig; Tapas K. Mallick; Duncan H. Gregory

doi:10.1002/aenm.201602328

Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

Guang Han, Srinivasa Popuri, Heather F. Greer, Lourdes F. Llin, Jan-Willem G Bos, Wuzong Z. Zhou, Douglas J. Paul, Hervé Ménard, Andrew R. Knox, Andrea Montecucco, Jonathan Siviter, Elena A. Man, Wen Guang Li, Manosh C. Paul, Min Gao, Tracy Sweet, Robert Freer, Feridoon Azough, Hasan Baig, Tapas K. MallickDuncan H. Gregory

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Abstract

An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

Original language	English
Article number	1602328
Number of pages	7
Journal	Advanced Energy Materials
Volume	7
Issue number	13
Early online date	20 Feb 2017
DOIs	https://doi.org/10.1002/aenm.201602328
Publication status	Published - 5 Jul 2017

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This is the peer reviewed version of the following article: G. Han, S. R. Popuri, H. F. Greer, L. F. Llin, J.-W. G. Bos, W. Z. Zhou, D. J. Paul, H. Ménard, A. R. Knox, A. Montecucco, J. Siviter, E. A. Man, W.-g. Li, M. C. Paul, M. Gao, T. Sweet, R. Freer, F. Azough, H. Baig, T. K. Mallick, D. H. Gregory, Adv. Energy Mater. 2017, 1602328, which has been published in final form at http://dx.doi.org/10.1002/aenm.201602328. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
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Han, G., Popuri, S., Greer, H. F., Llin, L. F., Bos, J.-W. G., Zhou, W. Z., Paul, D. J., Ménard, H., Knox, A. R., Montecucco, A., Siviter, J., Man, E. A., Li, W. G., Paul, M. C., Gao, M., Sweet, T., Freer, R., Azough, F., Baig, H., ... Gregory, D. H. (2017). Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials. Advanced Energy Materials, 7(13), Article 1602328. https://doi.org/10.1002/aenm.201602328

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title = "Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials",

abstract = "An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.",

author = "Guang Han and Srinivasa Popuri and Greer, {Heather F.} and Llin, {Lourdes F.} and Bos, {Jan-Willem G} and Zhou, {Wuzong Z.} and Paul, {Douglas J.} and Herv{\'e} M{\'e}nard and Knox, {Andrew R.} and Andrea Montecucco and Jonathan Siviter and Man, {Elena A.} and Li, {Wen Guang} and Paul, {Manosh C.} and Min Gao and Tracy Sweet and Robert Freer and Feridoon Azough and Hasan Baig and Mallick, {Tapas K.} and Gregory, {Duncan H.}",

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month = jul,

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doi = "10.1002/aenm.201602328",

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Han, G, Popuri, S, Greer, HF, Llin, LF, Bos, J-WG, Zhou, WZ, Paul, DJ, Ménard, H, Knox, AR, Montecucco, A, Siviter, J, Man, EA, Li, WG, Paul, MC, Gao, M, Sweet, T, Freer, R, Azough, F, Baig, H, Mallick, TK & Gregory, DH 2017, 'Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials', Advanced Energy Materials, vol. 7, no. 13, 1602328. https://doi.org/10.1002/aenm.201602328

TY - JOUR

T1 - Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

AU - Han, Guang

AU - Popuri, Srinivasa

AU - Greer, Heather F.

AU - Llin, Lourdes F.

AU - Bos, Jan-Willem G

AU - Zhou, Wuzong Z.

AU - Paul, Douglas J.

AU - Ménard, Hervé

AU - Knox, Andrew R.

AU - Montecucco, Andrea

AU - Siviter, Jonathan

AU - Man, Elena A.

AU - Li, Wen Guang

AU - Paul, Manosh C.

AU - Gao, Min

AU - Sweet, Tracy

AU - Freer, Robert

AU - Azough, Feridoon

AU - Baig, Hasan

AU - Mallick, Tapas K.

AU - Gregory, Duncan H.

PY - 2017/7/5

Y1 - 2017/7/5

N2 - An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

AB - An aqueous solution method is developed for the facile synthesis of Cl-containing SnSe nanoparticles in 10 g quantities per batch. The particle size and Cl concentration of the nanoparticles can be efficiently tuned as a function of reaction duration. Hot pressing produces n-type Cl-doped SnSe nanostructured compacts with thermoelectric power factors optimized via control of Cl dopant concentration. This approach, combining an energy-efficient solution synthesis with hot pressing, provides a simple, rapid, and low-cost route to high performance n-type SnSe thermoelectric materials.

U2 - 10.1002/aenm.201602328

DO - 10.1002/aenm.201602328

M3 - Article

SN - 1614-6832

VL - 7

JO - Advanced Energy Materials

JF - Advanced Energy Materials

IS - 13

M1 - 1602328

ER -

Chlorine-Enabled Electron Doping in Solution-Synthesized SnSe Thermoelectric Nanomaterials

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