TY - JOUR
T1 - Chemical transformations of solvent-derived ozonolysis products
T2 - Improved synthesis of polycyclic 1,2,4,6-tetroxepanes from α-alkoxy α′-hydroperoxy cyclic ethers and aldehydes
AU - McCullough, Kevin J.
AU - Ushigoe, Yoshihiro
AU - Tanaka, Shogo
AU - Masuyama, Araki
AU - Nojima, Masatomo
PY - 1998
Y1 - 1998
N2 - a-Alkoxy a'-hydroperoxy cyclic ethers condense with aliphatic aldehydes under acidic conditions to produce the bicyclic 1,2,4,6-tetroxepanes. By X-ray crystallographic analysis, the tetroxepanes 5b and 12b, derived from cyclocondensation of the hydroperoxides 4 and 8 respectively with acetaldehyde, were shown to be exo-isomers.
AB - a-Alkoxy a'-hydroperoxy cyclic ethers condense with aliphatic aldehydes under acidic conditions to produce the bicyclic 1,2,4,6-tetroxepanes. By X-ray crystallographic analysis, the tetroxepanes 5b and 12b, derived from cyclocondensation of the hydroperoxides 4 and 8 respectively with acetaldehyde, were shown to be exo-isomers.
UR - http://www.scopus.com/inward/record.url?scp=33751303798&partnerID=8YFLogxK
M3 - Article
SN - 0300-922X
SP - 3053
EP - 3057
JO - Journal of the Chemical Society, Perkin Transactions 1
JF - Journal of the Chemical Society, Perkin Transactions 1
IS - 18
ER -