Chemical thermometers in megawatt infrared laser chemistry: The decomposition of cyclobutanone sensitized by ammonia

Colin Steel; Vladimir Starov; Rinaldo Leo; Philip John; R. G  Harrison

Chemical thermometers in megawatt infrared laser chemistry: The decomposition of cyclobutanone sensitized by ammonia

Colin Steel, Vladimir Starov, Rinaldo Leo, Philip John, R. G Harrison

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Ammonia excited by CO₂ laser radiation may be used to sensitize unimolecular reactions of compounds which do not absorb the radiation directly at the chosen frequency. If cyclobutanone is present as a minor component then analysis of the products formed yields information as to the effective temperature reached by the system and the time the latter remains at this temperature. © 1979.

Original language	English
Pages (from-to)	121-124
Number of pages	4
Journal	Chemical Physics Letters
Volume	62
Issue number	1
Publication status	Published - 15 Mar 1979

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title = "Chemical thermometers in megawatt infrared laser chemistry: The decomposition of cyclobutanone sensitized by ammonia",

abstract = "Ammonia excited by CO2 laser radiation may be used to sensitize unimolecular reactions of compounds which do not absorb the radiation directly at the chosen frequency. If cyclobutanone is present as a minor component then analysis of the products formed yields information as to the effective temperature reached by the system and the time the latter remains at this temperature. {\textcopyright} 1979.",

author = "Colin Steel and Vladimir Starov and Rinaldo Leo and Philip John and Harrison, {R. G}",

year = "1979",

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T1 - Chemical thermometers in megawatt infrared laser chemistry

T2 - The decomposition of cyclobutanone sensitized by ammonia

AU - Steel, Colin

AU - Starov, Vladimir

AU - Leo, Rinaldo

AU - John, Philip

AU - Harrison, R. G

PY - 1979/3/15

Y1 - 1979/3/15

N2 - Ammonia excited by CO2 laser radiation may be used to sensitize unimolecular reactions of compounds which do not absorb the radiation directly at the chosen frequency. If cyclobutanone is present as a minor component then analysis of the products formed yields information as to the effective temperature reached by the system and the time the latter remains at this temperature. © 1979.

AB - Ammonia excited by CO2 laser radiation may be used to sensitize unimolecular reactions of compounds which do not absorb the radiation directly at the chosen frequency. If cyclobutanone is present as a minor component then analysis of the products formed yields information as to the effective temperature reached by the system and the time the latter remains at this temperature. © 1979.

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M3 - Article

SN - 0009-2614

VL - 62

SP - 121

EP - 124

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Chemical thermometers in megawatt infrared laser chemistry: The decomposition of cyclobutanone sensitized by ammonia

Abstract

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