TY - JOUR
T1 - CF2 emission during vacuum ultraviolet photodissociation of CF2Br2
AU - Johnson, C. A F
AU - Ross, Hilary J.
PY - 1978
Y1 - 1978
N2 - Photolysis of CF2Br2 at wavelengths shorter than 135 nm leads to the production of electronically excited CF2. At low pressure fluorescence is observed over the range 230-340 nm. Considerable vibrational excitation of the CF2 is evident. The CF2 fluorescence is quenched by H2, D2, CO and CO2 with rate constants of 5.6 × 109, 2.7 × 109, 4 × 1010 and 3.2 × 1010 dm3 mol -1 s-1, respectively.
AB - Photolysis of CF2Br2 at wavelengths shorter than 135 nm leads to the production of electronically excited CF2. At low pressure fluorescence is observed over the range 230-340 nm. Considerable vibrational excitation of the CF2 is evident. The CF2 fluorescence is quenched by H2, D2, CO and CO2 with rate constants of 5.6 × 109, 2.7 × 109, 4 × 1010 and 3.2 × 1010 dm3 mol -1 s-1, respectively.
UR - http://www.scopus.com/inward/record.url?scp=0005545860&partnerID=8YFLogxK
U2 - 10.1039/F19787402930
DO - 10.1039/F19787402930
M3 - Article
SN - 0300-9599
VL - 74
SP - 2930
EP - 2934
JO - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
JF - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
ER -