C,C'-Ru to C,B'-Ru isomerisation in bis(phosphine)Ru complexes of [1,1'-bis(ortho-carborane)]

Rebekah J. Jeans; Georgina M. Rosair; Alan J. Welch

doi:10.1039/d1cc06119d

C,C'-Ru to C,B'-Ru isomerisation in bis(phosphine)Ru complexes of [1,1'-bis(ortho-carborane)]

Rebekah J. Jeans, Georgina M. Rosair, Alan J. Welch

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

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Abstract

We report herein the first example of the controlled isomerisation of a C,C'-bound (to metal) bis(ortho-carborane) ligand to C,B'-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating properties this transformation allows the reactivity of the metal centre to be fine-tuned.

Original language	English
Pages (from-to)	64-67
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	1
Early online date	1 Dec 2021
DOIs	https://doi.org/10.1039/d1cc06119d
Publication status	Published - 4 Jan 2022

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "C,C'-Ru to C,B'-Ru isomerisation in bis(phosphine)Ru complexes of [1,1'-bis(ortho-carborane)]",

abstract = "We report herein the first example of the controlled isomerisation of a C,C'-bound (to metal) bis(ortho-carborane) ligand to C,B'-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating properties this transformation allows the reactivity of the metal centre to be fine-tuned.",

author = "Jeans, \{Rebekah J.\} and Rosair, \{Georgina M.\} and Welch, \{Alan J.\}",

note = "Funding Information: We thank the Engineering \& Physical Sciences Research Council and the CRITICAT Centre for Doctoral Training for a PhD studentship awarded to R. J. J. (grant no. EP/L016419/1). We also thank Prof. S. A. Macgregor for many helpful discussions. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

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AU - Rosair, Georgina M.

AU - Welch, Alan J.

N1 - Funding Information: We thank the Engineering & Physical Sciences Research Council and the CRITICAT Centre for Doctoral Training for a PhD studentship awarded to R. J. J. (grant no. EP/L016419/1). We also thank Prof. S. A. Macgregor for many helpful discussions. Publisher Copyright: © The Royal Society of Chemistry 2021.

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N2 - We report herein the first example of the controlled isomerisation of a C,C'-bound (to metal) bis(ortho-carborane) ligand to C,B'-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating properties this transformation allows the reactivity of the metal centre to be fine-tuned.

AB - We report herein the first example of the controlled isomerisation of a C,C'-bound (to metal) bis(ortho-carborane) ligand to C,B'-bound with no other change in the molecule. Since the C and B vertices of carboranes have different electron-donating properties this transformation allows the reactivity of the metal centre to be fine-tuned.

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DO - 10.1039/d1cc06119d

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JF - Chemical Communications

IS - 1

ER -

C,C'-Ru to C,B'-Ru isomerisation in bis(phosphine)Ru complexes of [1,1'-bis(ortho-carborane)]

Abstract

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