Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition

Robyn E. Fairbairn; Ross McLellan; Ruaraidh D. McIntosh; Stephanie M. Taylor; Euan K. Brechin; Scott J. Dalgarno

doi:10.1039/c2cc33166g

Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition

Robyn E. Fairbairn, Ross McLellan, Ruaraidh D. McIntosh, Stephanie M. Taylor, Euan K. Brechin, Scott J. Dalgarno

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Rare-earth octahedra have been previously synthesised using p-tert-butylcalix[4]arene as a cluster support. Introduction of a heteroatom bridge in the calixarene framework, with concomitant alteration to the nature of the metal binding pocket, influences lanthanide composition in the cluster.

Original language	English
Pages (from-to)	8493-8495
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	68
DOIs	https://doi.org/10.1039/c2cc33166g
Publication status	Published - 2012

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title = "Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition",

abstract = "Rare-earth octahedra have been previously synthesised using p-tert-butylcalix[4]arene as a cluster support. Introduction of a heteroatom bridge in the calixarene framework, with concomitant alteration to the nature of the metal binding pocket, influences lanthanide composition in the cluster.",

author = "Fairbairn, {Robyn E.} and Ross McLellan and McIntosh, {Ruaraidh D.} and Taylor, {Stephanie M.} and Brechin, {Euan K.} and Dalgarno, {Scott J.}",

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AU - Fairbairn, Robyn E.

AU - McLellan, Ross

AU - McIntosh, Ruaraidh D.

AU - Taylor, Stephanie M.

AU - Brechin, Euan K.

AU - Dalgarno, Scott J.

PY - 2012

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N2 - Rare-earth octahedra have been previously synthesised using p-tert-butylcalix[4]arene as a cluster support. Introduction of a heteroatom bridge in the calixarene framework, with concomitant alteration to the nature of the metal binding pocket, influences lanthanide composition in the cluster.

AB - Rare-earth octahedra have been previously synthesised using p-tert-butylcalix[4]arene as a cluster support. Introduction of a heteroatom bridge in the calixarene framework, with concomitant alteration to the nature of the metal binding pocket, influences lanthanide composition in the cluster.

U2 - 10.1039/c2cc33166g

DO - 10.1039/c2cc33166g

M3 - Article

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SN - 1359-7345

VL - 48

SP - 8493

EP - 8495

JO - Chemical Communications

JF - Chemical Communications

IS - 68

ER -

Calixarene-supported rare-earth clusters: heteroatom bridge influences cluster composition

Abstract

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