Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Stephanie M. Taylor; Ruaraidh D. McIntosh; Christine M. Beavers; Simon J. Teat; Stergios Piligkos; Scott J. Dalgarno; Euan K. Brechin

doi:10.1039/c0cc04466k

Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Stephanie M. Taylor
, Ruaraidh D. McIntosh
, Christine M. Beavers
, Simon J. Teat
, Stergios Piligkos^*
, Scott J. Dalgarno
, Euan K. Brechin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

58 Citations (Scopus)

Abstract

Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

Original language	English
Pages (from-to)	1440-1442
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	5
DOIs	https://doi.org/10.1039/c0cc04466k
Publication status	Published - 7 Feb 2011

Keywords

METAL
CAPSULES
VALENCE MNIIMNIII COMPLEXES
CALIXARENES
MAGNETS

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10.1039/c0cc04466k

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title = "Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers",

abstract = "Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.",

keywords = "METAL, CAPSULES, VALENCE MNIIMNIII COMPLEXES, CALIXARENES, MAGNETS",

author = "Taylor, \{Stephanie M.\} and McIntosh, \{Ruaraidh D.\} and Beavers, \{Christine M.\} and Teat, \{Simon J.\} and Stergios Piligkos and Dalgarno, \{Scott J.\} and Brechin, \{Euan K.\}",

year = "2011",

month = feb,

day = "7",

doi = "10.1039/c0cc04466k",

language = "English",

volume = "47",

pages = "1440--1442",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

AU - Taylor, Stephanie M.

AU - McIntosh, Ruaraidh D.

AU - Beavers, Christine M.

AU - Teat, Simon J.

AU - Piligkos, Stergios

AU - Dalgarno, Scott J.

AU - Brechin, Euan K.

PY - 2011/2/7

Y1 - 2011/2/7

N2 - Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

AB - Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

KW - METAL

KW - CAPSULES

KW - VALENCE MNIIMNIII COMPLEXES

KW - CALIXARENES

KW - MAGNETS

UR - https://www.scopus.com/pages/publications/78751523198

U2 - 10.1039/c0cc04466k

DO - 10.1039/c0cc04466k

M3 - Article

C2 - 21161081

SN - 1359-7345

VL - 47

SP - 1440

EP - 1442

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Calix[4]arene supported clusters: a dimer of [(MnMnII)-Mn-III] dimers

Abstract

Keywords

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