Abstract
Phosphinate ligands allow for the transformation of a calix[4]arene supported [(Mn2Mn2II)-Mn-III] tetramer cluster motif into an unusual [(MnMnII)-Mn-III](2) dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.
Original language | English |
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Pages (from-to) | 1440-1442 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 47 |
Issue number | 5 |
DOIs | |
Publication status | Published - 7 Feb 2011 |
Keywords
- METAL
- CAPSULES
- VALENCE MNIIMNIII COMPLEXES
- CALIXARENES
- MAGNETS