Calix[4]arene-based single-molecule magnets

Georgios Karotsis, Simon J. Teat, Wolfgang Wernsdorfer, Stergios Piligkos, Scott J. Dalgarno, Euan K. Brechin

Research output: Contribution to journalArticle

90 Citations (Scopus)

Abstract

Protective skin: Single-molecule magnets (SMMs) that are protected by two calix[4]arenes have been synthesized (see picture: Mn purple, O red, N blue, C gray). The calixarene allows supramolecular isolation of the SMM, and alteration of its upper rim provides control over the orientation in the solid state by altering the distances between layers. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Original languageEnglish
Pages (from-to)8285-8288
Number of pages4
JournalAngewandte Chemie International Edition
Volume48
Issue number44
DOIs
Publication statusPublished - 19 Oct 2009

Keywords

  • Calixarenes
  • Magnetic properties
  • Manganese
  • Self-assembly
  • Supramolecular chemistry

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    Karotsis, G., Teat, S. J., Wernsdorfer, W., Piligkos, S., Dalgarno, S. J., & Brechin, E. K. (2009). Calix[4]arene-based single-molecule magnets. Angewandte Chemie International Edition, 48(44), 8285-8288. https://doi.org/10.1002/anie.200904094