[C7H10N][In3Se5]: A Layered Selenide with Two Indium Coordination Environments

Sarah J. Ewing; Anthony V. Powell; Paz Vaqueiro

doi:10.1021/ic300861h

[C7H10N][In3Se5]: A Layered Selenide with Two Indium Coordination Environments

Sarah J. Ewing, Anthony V. Powell, Paz Vaqueiro

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new layered indium selenide, [C7H10N][In3Se5] (1), has been prepared solvothermally using 3,5-dimethylpyridine as a solvent and structure-directing agent. This material, which was characterized by single-crystal and powder X-ray diffraction, thermogravimetric analysis, UV-vis diffuse-reflectance spectroscopy, IR. spectroscopy, and elemental analysis, crystallizes in the monoclinic space group P2(1)/c [a = 3.9990(4) angstrom, b = 16.7858(15) angstrom, c = 23.930(2) angstrom, and beta = 94.728(4)degrees], The crystal structure of 1 contains anionic layers of stoichiometry [In3Se5] - in which indium atoms with octahedral and tetrahedral coordination coexist. The [In3Se5](-) layers are interspaced by monoprotonated 3,5-dimethylpyridinium cations. A closely related material, [C7H10N][In3Se5] (2), was obtained when using 2,6-dimethylpyridine instead of 3,5-dimethylpyridine.

Original language	English
Pages (from-to)	7404-7409
Number of pages	6
Journal	Inorganic Chemistry
Volume	51
Issue number	13
DOIs	https://doi.org/10.1021/ic300861h
Publication status	Published - 2 Jul 2012

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@article{884445099019449ea9da82e5282dbf27,

title = "[C7H10N][In3Se5]: A Layered Selenide with Two Indium Coordination Environments",

abstract = "A new layered indium selenide, [C7H10N][In3Se5] (1), has been prepared solvothermally using 3,5-dimethylpyridine as a solvent and structure-directing agent. This material, which was characterized by single-crystal and powder X-ray diffraction, thermogravimetric analysis, UV-vis diffuse-reflectance spectroscopy, IR. spectroscopy, and elemental analysis, crystallizes in the monoclinic space group P2(1)/c [a = 3.9990(4) angstrom, b = 16.7858(15) angstrom, c = 23.930(2) angstrom, and beta = 94.728(4)degrees], The crystal structure of 1 contains anionic layers of stoichiometry [In3Se5] - in which indium atoms with octahedral and tetrahedral coordination coexist. The [In3Se5](-) layers are interspaced by monoprotonated 3,5-dimethylpyridinium cations. A closely related material, [C7H10N][In3Se5] (2), was obtained when using 2,6-dimethylpyridine instead of 3,5-dimethylpyridine.",

author = "Ewing, {Sarah J.} and Powell, {Anthony V.} and Paz Vaqueiro",

year = "2012",

month = jul,

day = "2",

doi = "10.1021/ic300861h",

language = "English",

volume = "51",

pages = "7404--7409",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - [C7H10N][In3Se5]: A Layered Selenide with Two Indium Coordination Environments

AU - Ewing, Sarah J.

AU - Powell, Anthony V.

AU - Vaqueiro, Paz

PY - 2012/7/2

Y1 - 2012/7/2

N2 - A new layered indium selenide, [C7H10N][In3Se5] (1), has been prepared solvothermally using 3,5-dimethylpyridine as a solvent and structure-directing agent. This material, which was characterized by single-crystal and powder X-ray diffraction, thermogravimetric analysis, UV-vis diffuse-reflectance spectroscopy, IR. spectroscopy, and elemental analysis, crystallizes in the monoclinic space group P2(1)/c [a = 3.9990(4) angstrom, b = 16.7858(15) angstrom, c = 23.930(2) angstrom, and beta = 94.728(4)degrees], The crystal structure of 1 contains anionic layers of stoichiometry [In3Se5] - in which indium atoms with octahedral and tetrahedral coordination coexist. The [In3Se5](-) layers are interspaced by monoprotonated 3,5-dimethylpyridinium cations. A closely related material, [C7H10N][In3Se5] (2), was obtained when using 2,6-dimethylpyridine instead of 3,5-dimethylpyridine.

AB - A new layered indium selenide, [C7H10N][In3Se5] (1), has been prepared solvothermally using 3,5-dimethylpyridine as a solvent and structure-directing agent. This material, which was characterized by single-crystal and powder X-ray diffraction, thermogravimetric analysis, UV-vis diffuse-reflectance spectroscopy, IR. spectroscopy, and elemental analysis, crystallizes in the monoclinic space group P2(1)/c [a = 3.9990(4) angstrom, b = 16.7858(15) angstrom, c = 23.930(2) angstrom, and beta = 94.728(4)degrees], The crystal structure of 1 contains anionic layers of stoichiometry [In3Se5] - in which indium atoms with octahedral and tetrahedral coordination coexist. The [In3Se5](-) layers are interspaced by monoprotonated 3,5-dimethylpyridinium cations. A closely related material, [C7H10N][In3Se5] (2), was obtained when using 2,6-dimethylpyridine instead of 3,5-dimethylpyridine.

U2 - 10.1021/ic300861h

DO - 10.1021/ic300861h

M3 - Article

SN - 0020-1669

VL - 51

SP - 7404

EP - 7409

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

[C7H10N][In3Se5]: A Layered Selenide with Two Indium Coordination Environments

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