C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide

Peter J. Carmichael; Brian G. Gowenlock; C. A F Johnson

C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide

Peter J. Carmichael, Brian G. Gowenlock, C. A F Johnson

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

37 Citations (Scopus)

Abstract

Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol^-1 for D(CF ₃-NO), 32 for D(CCl₃-NO), 32 for D(C₆F ₅-NO), and 29 for D(Bu^tNO-Bu^t). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C ₆F₅-NO) is discussed.

Original language	English
Pages (from-to)	1853-1856
Number of pages	4
Journal	Journal of the Chemical Society, Perkin Transactions 2
Issue number	14
Publication status	Published - 1973

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@article{3ae65ac459ce4958b086ca81338c0c75,

title = "C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide",

abstract = "Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.",

author = "Carmichael, \{Peter J.\} and Gowenlock, \{Brian G.\} and Johnson, \{C. A F\}",

year = "1973",

language = "English",

pages = "1853--1856",

journal = "Journal of the Chemical Society, Perkin Transactions 2",

issn = "1472-779X",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide

AU - Carmichael, Peter J.

AU - Gowenlock, Brian G.

AU - Johnson, C. A F

PY - 1973

Y1 - 1973

N2 - Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.

AB - Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.

M3 - Article

SN - 1472-779X

SP - 1853

EP - 1856

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

IS - 14

ER -

C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide

Abstract

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