C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide

Peter J. Carmichael, Brian G. Gowenlock, C. A F Johnson

Research output: Contribution to journalArticle

Abstract

Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.

Original languageEnglish
Pages (from-to)1853-1856
Number of pages4
JournalJournal of the Chemical Society, Perkin Transactions 2
Issue number14
Publication statusPublished - 1973

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Nitroso Compounds
Electrons
di-t-butyl nitroxide

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title = "C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide",
abstract = "Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.",
author = "Carmichael, {Peter J.} and Gowenlock, {Brian G.} and Johnson, {C. A F}",
year = "1973",
language = "English",
pages = "1853--1856",
journal = "Journal of the Chemical Society, Perkin Transactions 2",
issn = "1472-779X",
publisher = "Royal Society of Chemistry",
number = "14",

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C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide. / Carmichael, Peter J.; Gowenlock, Brian G.; Johnson, C. A F.

In: Journal of the Chemical Society, Perkin Transactions 2, No. 14, 1973, p. 1853-1856.

Research output: Contribution to journalArticle

TY - JOUR

T1 - C-N bond dissociation energies in some halogenated C-nitroso-compounds and in Di-t-butyl nitroxide

AU - Carmichael, Peter J.

AU - Gowenlock, Brian G.

AU - Johnson, C. A F

PY - 1973

Y1 - 1973

N2 - Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.

AB - Measurements of the R-NO bond dissociation energy in some halogenated C-nitroso-compounds and in di-t-butyl nitroxide have been made using an electron impact method. The values obtained are: 31 kcal mol-1 for D(CF 3-NO), 32 for D(CCl3-NO), 32 for D(C6F 5-NO), and 29 for D(ButNO-But). These values are compared with bond dissociation energies in a range of other nitroso-compounds, and general relationships between structural parameters and bond dissociation energies are discussed. The anomalous value for D(C 6F5-NO) is discussed.

M3 - Article

SP - 1853

EP - 1856

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

SN - 1472-779X

IS - 14

ER -