Bis(acetylido) complexes of ruthenium(II) bearing monodentate phosphane ligands

Leslie D. Field, Alison M. Magill, Scott J. Dalgarno, Paul Jensen

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

Terminal acetylenes react with cis-RuMe2(PMe3) 4 to form the bis(acetylido) complexes cis/trans-Ru(C=CR) 2(PMe3)4 in good yield. The structures of trans-2 (R = Ph), cis-3 (R = p-C6H4-OMe), trans-4 (R = p-C6H4-Me), cis-6 (R = Me), trans-7 (R = SiMe3) and cis-8 (R = H) were determined by X-ray crystallography. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Original languageEnglish
Pages (from-to)4248-4254
Number of pages7
JournalEuropean Journal of Inorganic Chemistry
Issue number27
DOIs
Publication statusPublished - Sep 2008

Keywords

  • Alkyne ligands
  • Phosphane ligands
  • Ruthenium

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