Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism

Marco Coletta; Ross McLellan; Paul Murphy; Bernhard T Leube; Sergio Sanz; Rob Clowes; Kevin J. Gagnon; Simon J. Teat; Andrew I. Cooper; Martin J Paterson; Euan K. Brechin; Scott J Dalgarno

doi:10.1002/chem.201600762

Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism

Marco Coletta, Ross McLellan, Paul Murphy, Bernhard T Leube, Sergio Sanz, Rob Clowes, Kevin J. Gagnon, Simon J. Teat, Andrew I. Cooper, Martin J Paterson, Euan K. Brechin, Scott J Dalgarno

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Abstract

Calix[4]arenes (C[4]s) are versatile platforms for the construction of polymetallic clusters containing paramagnetic metal ions. Synthetic modification at the C[4] methylene bridge allows for the design of bis-C[4]s that, depending on the linker employed, can be used to either dictate which clusters can be formed or direct the assembly of a new metal–organic polyhedron (MOP). The assembly resulting from the latter approach displays thermal stability and uptake of N2 or H2 gas, confirming that this is a viable route to the synthesis of new, functional supramolecular architectures.

Original language	English
Pages (from-to)	8791–8795
Number of pages	5
Journal	Chemistry - A European Journal
Volume	22
Issue number	26
Early online date	11 May 2016
DOIs	https://doi.org/10.1002/chem.201600762
Publication status	Published - 20 Jun 2016

Keywords

calixarenes
clusters
directed assembly
gas storage
metal-organic polyhedron

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10.1002/chem.201600762

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This is the peer reviewed version of the following article: Coletta, M., McLellan, R., Murphy, P., Leube, B. T., Sanz, S., Clowes, R., Gagnon, K. J., Teat, S. J., Cooper, A. I., Paterson, M. J., Brechin, E. K. and Dalgarno, S. J. (2016), Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism. Chem. Eur. J., which has been published in final form at doi:10.1002/chem.201600762. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
Accepted author manuscript, 3.74 MBLicence: CC BY-NC

Scott J. Dalgarno
- s.j.dalgarnohw.acuk
- School of Engineering & Physical Sciences - Professor
- School of Engineering & Physical Sciences, Institute of Chemical Sciences - Professor
Person: Academic (Research & Teaching)

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Coletta, M., McLellan, R., Murphy, P., Leube, B. T., Sanz, S., Clowes, R., Gagnon, K. J., Teat, S. J., Cooper, A. I., Paterson, M. J., Brechin, E. K., & Dalgarno, S. J. (2016). Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism. Chemistry - A European Journal, 22(26), 8791–8795. https://doi.org/10.1002/chem.201600762

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abstract = "Calix[4]arenes (C[4]s) are versatile platforms for the construction of polymetallic clusters containing paramagnetic metal ions. Synthetic modification at the C[4] methylene bridge allows for the design of bis-C[4]s that, depending on the linker employed, can be used to either dictate which clusters can be formed or direct the assembly of a new metal–organic polyhedron (MOP). The assembly resulting from the latter approach displays thermal stability and uptake of N2 or H2 gas, confirming that this is a viable route to the synthesis of new, functional supramolecular architectures.",

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AU - Sanz, Sergio

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AU - Dalgarno, Scott J

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AB - Calix[4]arenes (C[4]s) are versatile platforms for the construction of polymetallic clusters containing paramagnetic metal ions. Synthetic modification at the C[4] methylene bridge allows for the design of bis-C[4]s that, depending on the linker employed, can be used to either dictate which clusters can be formed or direct the assembly of a new metal–organic polyhedron (MOP). The assembly resulting from the latter approach displays thermal stability and uptake of N2 or H2 gas, confirming that this is a viable route to the synthesis of new, functional supramolecular architectures.

KW - calixarenes

KW - clusters

KW - directed assembly

KW - gas storage

KW - metal-organic polyhedron

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Bis-Calix[4]arenes: From Ligand Design to the Directed Assembly of a Metal–Organic Trigonal Antiprism

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