Benzylidene acetals of the D-ribonolactones: A structural reassessment

Neil Baggett, J. Grant Buchanan, Moutie Y. Fatah, C. H. Lachut, Kevin J. McCullough, John M. Webber

Research output: Contribution to journalArticle

Abstract

The product of the reaction of D-ribono-1,4-lactone with benzaldehyde and concentrated HCl has been shown, by X-ray crystallography of its acetate, to be 3,4-O-(R)-benzylidene-D-ribono-1,5-lactone and not the 3,5-acetal as previously suggested; with ZnCl2 as catalyst the products are 2,3-O-(R)- and -(S)-benzylidene-D-ribono-1,4-lactone, the former preponderating.

Original languageEnglish
Pages (from-to)1826-1827
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number24
Publication statusPublished - 1985

Fingerprint Dive into the research topics of 'Benzylidene acetals of the D-ribonolactones: A structural reassessment'. Together they form a unique fingerprint.

  • Cite this

    Baggett, N., Buchanan, J. G., Fatah, M. Y., Lachut, C. H., McCullough, K. J., & Webber, J. M. (1985). Benzylidene acetals of the D-ribonolactones: A structural reassessment. Journal of the Chemical Society, Chemical Communications, (24), 1826-1827.