Atmospheric CO2 Sequestration in Iron and Steel Slag: Consett, County Durham, United Kingdom

William Matthew Mayes, Alex L. Riley, Helena I. Gomes, Peter Brabham, Joanna Hamlyn, Huw Pullin, Phil Renforth

Research output: Contribution to journalArticle

15 Citations (Scopus)
14 Downloads (Pure)

Abstract

Carbonate formation in waste from the steel industry could constitute a nontrivial proportion of the global requirements for removing carbon dioxide from the atmosphere at a potentially low cost. To utilize this potential, we examined atmospheric carbon dioxide sequestration in a >20 million ton legacy slag deposit in northern England, United Kingdom. Carbonates formed from the drainage water of the heap had stable carbon and oxygen isotope values between -12 and -25 ‰ and -5 and -18 ‰ for δ13C and δ18O, respectively, suggesting atmospheric carbon dioxide sequestration in high-pH solutions. From the analyses of solution saturation states, we estimate that between 280 and 2900 tons of CO2 have precipitated from the drainage waters. However, by combining a 37 year long data set of the drainage water chemistry with geospatial analysis, we estimate that <1% of the maximum carbon-capture potential of the deposit may have been realized. This implies that uncontrolled deposition of slag is insufficient to maximize carbon sequestration, and there may be considerable quantities of unreacted legacy deposits available for atmospheric carbon sequestration.

Original languageEnglish
Pages (from-to)7892-7900
Number of pages9
JournalEnvironmental Science and Technology
Volume52
Issue number14
DOIs
Publication statusPublished - 17 Jul 2018

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

Fingerprint Dive into the research topics of 'Atmospheric CO<sub>2</sub> Sequestration in Iron and Steel Slag: Consett, County Durham, United Kingdom'. Together they form a unique fingerprint.

Cite this