Assignment of ring size in isopropylidene acetals by carbon-13 n.m.r. spectroscopy

J. Grant Buchanan, Alan R. Edgar, David I. Rawson, Parvin Shahidi, Richard H. Wightman

Research output: Contribution to journalArticle

Abstract

The 13C-n.m.r. spectra of a range of isopropylidene acetals of carbohydrates have been studied. Attention has been focussed on the chemical shifts of the acetal carbon and methyl groups of the acetals. These parameters are characteristic of ring-size (1,3-dioxolane, 1,3-dioxane, and 1,3-dioxepane) and can sometimes give further information on ring-fusions and conformations. An example is given of the application of the method to 1,3:2,4:5,6-tri-O-isopropylidene-d-glucitol. © 1982.

Original languageEnglish
Pages (from-to)75-86
Number of pages12
JournalCarbohydrate Research
Volume100
Issue number1
Publication statusPublished - 1982

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Acetals
Carbon
Spectroscopy
Sorbitol
Chemical shift
Conformations
Fusion reactions
Carbohydrates
propylene

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Buchanan, J. G., Edgar, A. R., Rawson, D. I., Shahidi, P., & Wightman, R. H. (1982). Assignment of ring size in isopropylidene acetals by carbon-13 n.m.r. spectroscopy. Carbohydrate Research, 100(1), 75-86.
Buchanan, J. Grant ; Edgar, Alan R. ; Rawson, David I. ; Shahidi, Parvin ; Wightman, Richard H. / Assignment of ring size in isopropylidene acetals by carbon-13 n.m.r. spectroscopy. In: Carbohydrate Research. 1982 ; Vol. 100, No. 1. pp. 75-86.
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Buchanan, JG, Edgar, AR, Rawson, DI, Shahidi, P & Wightman, RH 1982, 'Assignment of ring size in isopropylidene acetals by carbon-13 n.m.r. spectroscopy', Carbohydrate Research, vol. 100, no. 1, pp. 75-86.

Assignment of ring size in isopropylidene acetals by carbon-13 n.m.r. spectroscopy. / Buchanan, J. Grant; Edgar, Alan R.; Rawson, David I.; Shahidi, Parvin; Wightman, Richard H.

In: Carbohydrate Research, Vol. 100, No. 1, 1982, p. 75-86.

Research output: Contribution to journalArticle

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AU - Edgar, Alan R.

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Buchanan JG, Edgar AR, Rawson DI, Shahidi P, Wightman RH. Assignment of ring size in isopropylidene acetals by carbon-13 n.m.r. spectroscopy. Carbohydrate Research. 1982;100(1):75-86.