An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et3P)-μ4,6-or-7-{Co(PEt3)2-μ-(H)2}-1,2,4-C2CoB10H10]

Geoffrey K. Barker; Maria P. Garcia; Michael Green; F. Gordon A. Stone; Alan J. Welch

doi:10.1039/C39830000137

An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et₃P)-μ_4,6-or-7-{Co(PEt₃)₂-μ-(H)₂}-1,2,4-C₂CoB₁₀H₁₀]

Geoffrey K. Barker^*, Maria P. Garcia, Michael Green, F. Gordon A. Stone, Alan J. Welch

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Reaction (room temperature, toluene) of closo-1-Me-1,2-C₂B₁₀H₁₁ with two equivalents of [Co(PEt₃)₄] affords the title compound, structurally identified by X-ray crystallography.

Original language	English
Pages (from-to)	137-139
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	3
DOIs	https://doi.org/10.1039/C39830000137
Publication status	Published - 1983

ASJC Scopus subject areas

Molecular Medicine

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title = "An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et3P)-μ4,6-or-7-\{Co(PEt3)2-μ-(H)2\}-1,2,4-C2CoB10H10]",

abstract = " Reaction (room temperature, toluene) of closo-1-Me-1,2-C2B10H11 with two equivalents of [Co(PEt3)4] affords the title compound, structurally identified by X-ray crystallography. ",

author = "Barker, \{Geoffrey K.\} and Garcia, \{Maria P.\} and Michael Green and Stone, \{F. Gordon A.\} and Welch, \{Alan J.\}",

year = "1983",

doi = "10.1039/C39830000137",

language = "English",

pages = "137--139",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "3",

}

TY - JOUR

T1 - An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et3P)-μ4,6-or-7-{Co(PEt3)2-μ-(H)2}-1,2,4-C2CoB10H10]

AU - Barker, Geoffrey K.

AU - Garcia, Maria P.

AU - Green, Michael

AU - Stone, F. Gordon A.

AU - Welch, Alan J.

PY - 1983

Y1 - 1983

N2 - Reaction (room temperature, toluene) of closo-1-Me-1,2-C2B10H11 with two equivalents of [Co(PEt3)4] affords the title compound, structurally identified by X-ray crystallography.

AB - Reaction (room temperature, toluene) of closo-1-Me-1,2-C2B10H11 with two equivalents of [Co(PEt3)4] affords the title compound, structurally identified by X-ray crystallography.

UR - https://www.scopus.com/pages/publications/37049104654

U2 - 10.1039/C39830000137

DO - 10.1039/C39830000137

M3 - Article

AN - SCOPUS:37049104654

SN - 0022-4936

SP - 137

EP - 139

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 3

ER -

An unusual 13-vertex closo-carbacobaltaborane; synthesis and molecular structure of [1-Me-4-(Et₃P)-μ_4,6-or-7-{Co(PEt₃)₂-μ-(H)₂}-1,2,4-C₂CoB₁₀H₁₀]

Abstract

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