An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

A. S F Boyd; Graeme Cooke; F. M A Duclairoir; Vincent M. Rotello

doi:10.1016/S0040-4039(02)02574-1

An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

A. S F Boyd, Graeme Cooke, F. M A Duclairoir, Vincent M. Rotello

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3⁺· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 3²⁺ species at the working electrode via hydrogen bonded molecular recognition processes. © 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	303-306
Number of pages	4
Journal	Tetrahedron Letters
Volume	44
Issue number	2
DOIs	https://doi.org/10.1016/S0040-4039(02)02574-1
Publication status	Published - 6 Jan 2003

Keywords

Electrochemistry
Recognition
Tetrathiafulvalene

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10.1016/S0040-4039(02)02574-1

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abstract = "We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. {\textcopyright} 2002 Elsevier Science Ltd. All rights reserved.",

keywords = "Electrochemistry, Recognition, Tetrathiafulvalene",

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AU - Duclairoir, F. M A

AU - Rotello, Vincent M.

PY - 2003/1/6

Y1 - 2003/1/6

N2 - We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. © 2002 Elsevier Science Ltd. All rights reserved.

AB - We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. © 2002 Elsevier Science Ltd. All rights reserved.

KW - Electrochemistry

KW - Recognition

KW - Tetrathiafulvalene

UR - https://www.scopus.com/pages/publications/0037421076

U2 - 10.1016/S0040-4039(02)02574-1

DO - 10.1016/S0040-4039(02)02574-1

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 2

ER -

An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

Abstract

Keywords

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