An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

A. S F Boyd, Graeme Cooke, F. M A Duclairoir, Vincent M. Rotello

Research output: Contribution to journalArticle

Abstract

We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. © 2002 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)303-306
Number of pages4
JournalTetrahedron Letters
Volume44
Issue number2
DOIs
Publication statusPublished - 6 Jan 2003

Fingerprint

Molecular recognition
Hydrogen
Hydrogen bonds
Stabilization
Electrodes
tetrathiafulvalene
Oxidation-Reduction

Keywords

  • Electrochemistry
  • Recognition
  • Tetrathiafulvalene

Cite this

Boyd, A. S F ; Cooke, Graeme ; Duclairoir, F. M A ; Rotello, Vincent M. / An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution. In: Tetrahedron Letters. 2003 ; Vol. 44, No. 2. pp. 303-306.
@article{d3a66a6e5e5e406899a2879373cc7e43,
title = "An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution",
abstract = "We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. {\circledC} 2002 Elsevier Science Ltd. All rights reserved.",
keywords = "Electrochemistry, Recognition, Tetrathiafulvalene",
author = "Boyd, {A. S F} and Graeme Cooke and Duclairoir, {F. M A} and Rotello, {Vincent M.}",
year = "2003",
month = "1",
day = "6",
doi = "10.1016/S0040-4039(02)02574-1",
language = "English",
volume = "44",
pages = "303--306",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "2",

}

An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution. / Boyd, A. S F; Cooke, Graeme; Duclairoir, F. M A; Rotello, Vincent M.

In: Tetrahedron Letters, Vol. 44, No. 2, 06.01.2003, p. 303-306.

Research output: Contribution to journalArticle

TY - JOUR

T1 - An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

AU - Boyd, A. S F

AU - Cooke, Graeme

AU - Duclairoir, F. M A

AU - Rotello, Vincent M.

PY - 2003/1/6

Y1 - 2003/1/6

N2 - We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. © 2002 Elsevier Science Ltd. All rights reserved.

AB - We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3+· state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 32+ species at the working electrode via hydrogen bonded molecular recognition processes. © 2002 Elsevier Science Ltd. All rights reserved.

KW - Electrochemistry

KW - Recognition

KW - Tetrathiafulvalene

UR - http://www.scopus.com/inward/record.url?scp=0037421076&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(02)02574-1

DO - 10.1016/S0040-4039(02)02574-1

M3 - Article

VL - 44

SP - 303

EP - 306

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 2

ER -