An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene)

Martin R. Bryce; Graeme Cooke; F. M A Duclairoir; Vincent M. Rotello

doi:10.1016/S0040-4039(00)02167-5

An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene)

Martin R. Bryce, Graeme Cooke, F. M A Duclairoir, Vincent M. Rotello

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

This study has shown that easily oxidisable TTF units form charge-transfer (C-T) complexes with 7 which have the largest reported association constants to date. Replacing the sulfur of the TTF unit with selenium or extending the conjugated link between the two dithiole rings reduces the K_a of the complex relative to the parent derivative. © 2001 Published by Elsevier Science Ltd.

Original language	English
Pages (from-to)	1143-1145
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	6
DOIs	https://doi.org/10.1016/S0040-4039(00)02167-5
Publication status	Published - 5 Feb 2001

Access to Document

10.1016/S0040-4039(00)02167-5

Cite this

@article{f3b1369c405e495a89d1400787b36118,

title = "An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene)",

abstract = "This study has shown that easily oxidisable TTF units form charge-transfer (C-T) complexes with 7 which have the largest reported association constants to date. Replacing the sulfur of the TTF unit with selenium or extending the conjugated link between the two dithiole rings reduces the Ka of the complex relative to the parent derivative. {\textcopyright} 2001 Published by Elsevier Science Ltd.",

author = "Bryce, {Martin R.} and Graeme Cooke and Duclairoir, {F. M A} and Rotello, {Vincent M.}",

year = "2001",

month = feb,

day = "5",

doi = "10.1016/S0040-4039(00)02167-5",

language = "English",

volume = "42",

pages = "1143--1145",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "6",

}

TY - JOUR

T1 - An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene)

AU - Bryce, Martin R.

AU - Cooke, Graeme

AU - Duclairoir, F. M A

AU - Rotello, Vincent M.

PY - 2001/2/5

Y1 - 2001/2/5

N2 - This study has shown that easily oxidisable TTF units form charge-transfer (C-T) complexes with 7 which have the largest reported association constants to date. Replacing the sulfur of the TTF unit with selenium or extending the conjugated link between the two dithiole rings reduces the Ka of the complex relative to the parent derivative. © 2001 Published by Elsevier Science Ltd.

AB - This study has shown that easily oxidisable TTF units form charge-transfer (C-T) complexes with 7 which have the largest reported association constants to date. Replacing the sulfur of the TTF unit with selenium or extending the conjugated link between the two dithiole rings reduces the Ka of the complex relative to the parent derivative. © 2001 Published by Elsevier Science Ltd.

UR - http://www.scopus.com/inward/record.url?scp=0035808925&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)02167-5

DO - 10.1016/S0040-4039(00)02167-5

M3 - Article

SN - 0040-4039

VL - 42

SP - 1143

EP - 1145

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 6

ER -

An investigation of the complexation behaviour of structurally modified tetrathiafulvalene derivatives with the electron deficient cyclophane cyclobis(paraquat-p-phenylene)

Abstract

Access to Document

Other files and links

Fingerprint

Cite this