An indenide-tethered N-heterocyclic stannylene

Tobias Bischof, Kieren Evans, Mairi Haddow, Stephen M. Mansell

Research output: Contribution to journalArticle

Abstract

The structure of 2, C33H47LiN2O4Sn, at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η-2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.
Original languageEnglish
Pages (from-to)254-256
JournalActa Crystallographica Section E: Crystallographic Communications
Volume76
Issue numberPart 2
Early online date21 Jan 2020
DOIs
Publication statusPublished - Feb 2020

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abstract = "The structure of 2, C33H47LiN2O4Sn, at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η-2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.",
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An indenide-tethered N-heterocyclic stannylene. / Bischof, Tobias; Evans, Kieren; Haddow, Mairi; Mansell, Stephen M.

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 76, No. Part 2, 02.2020, p. 254-256.

Research output: Contribution to journalArticle

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AU - Bischof, Tobias

AU - Evans, Kieren

AU - Haddow, Mairi

AU - Mansell, Stephen M.

PY - 2020/2

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N2 - The structure of 2, C33H47LiN2O4Sn, at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η-2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.

AB - The structure of 2, C33H47LiN2O4Sn, at 100 K has monoclinic (P21/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn interacts in an η-2 fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclopentadienyl ligands and their derivatives.

U2 - 10.1107/S205698902000047X

DO - 10.1107/S205698902000047X

M3 - Article

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SP - 254

EP - 256

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

SN - 2056-9890

IS - Part 2

ER -