An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3

Peter G. Bruce; Jan Nowinski; Fiona M. Gray; Colin A. Vincent

An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO₄)₃

Peter G. Bruce
, Jan Nowinski
, Fiona M. Gray
, Colin A. Vincent

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The polymer electrolyte PEO:La(ClO₄)₃ has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg²⁺, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

Original language	English
Pages (from-to)	231-234
Number of pages	4
Journal	Solid State Ionics
Volume	38
Issue number	3-4
Publication status	Published - May 1990

Cite this

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title = "An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3",

abstract = "The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. {\textcopyright} 1990.",

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year = "1990",

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journal = "Solid State Ionics",

issn = "0167-2738",

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T1 - An anhydrous polymer electrolyte containing trivalent cations

T2 - Poly(ethylene oxide):La(ClO4)3

AU - Bruce, Peter G.

AU - Nowinski, Jan

AU - Gray, Fiona M.

AU - Vincent, Colin A.

PY - 1990/5

Y1 - 1990/5

N2 - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

AB - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

UR - https://www.scopus.com/pages/publications/0025425876

M3 - Article

SN - 0167-2738

VL - 38

SP - 231

EP - 234

JO - Solid State Ionics

JF - Solid State Ionics

IS - 3-4

ER -

An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO₄)₃

Abstract

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