An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3

Peter G. Bruce; Jan Nowinski; Fiona M. Gray; Colin A. Vincent

An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO₄)₃

Peter G. Bruce, Jan Nowinski, Fiona M. Gray, Colin A. Vincent

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article

Abstract

The polymer electrolyte PEO:La(ClO₄)₃ has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg²⁺, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

Original language	English
Pages (from-to)	231-234
Number of pages	4
Journal	Solid State Ionics
Volume	38
Issue number	3-4
Publication status	Published - May 1990

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title = "An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3",

abstract = "The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. {\textcopyright} 1990.",

author = "Bruce, {Peter G.} and Jan Nowinski and Gray, {Fiona M.} and Vincent, {Colin A.}",

year = "1990",

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journal = "Solid State Ionics",

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T2 - Poly(ethylene oxide):La(ClO4)3

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AU - Nowinski, Jan

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AU - Vincent, Colin A.

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N2 - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

AB - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

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M3 - Article

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SP - 231

EP - 234

JO - Solid State Ionics

JF - Solid State Ionics

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