Abstract
The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.
Original language | English |
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Pages (from-to) | 231-234 |
Number of pages | 4 |
Journal | Solid State Ionics |
Volume | 38 |
Issue number | 3-4 |
Publication status | Published - May 1990 |
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An anhydrous polymer electrolyte containing trivalent cations : Poly(ethylene oxide):La(ClO4)3. / Bruce, Peter G.; Nowinski, Jan; Gray, Fiona M.; Vincent, Colin A.
In: Solid State Ionics, Vol. 38, No. 3-4, 05.1990, p. 231-234.Research output: Contribution to journal › Article
TY - JOUR
T1 - An anhydrous polymer electrolyte containing trivalent cations
T2 - Poly(ethylene oxide):La(ClO4)3
AU - Bruce, Peter G.
AU - Nowinski, Jan
AU - Gray, Fiona M.
AU - Vincent, Colin A.
PY - 1990/5
Y1 - 1990/5
N2 - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.
AB - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.
UR - http://www.scopus.com/inward/record.url?scp=0025425876&partnerID=8YFLogxK
M3 - Article
VL - 38
SP - 231
EP - 234
JO - Solid State Ionics
JF - Solid State Ionics
SN - 0167-2738
IS - 3-4
ER -