An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3

Peter G. Bruce; Jan Nowinski; Fiona M. Gray; Colin A. Vincent

An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO₄)₃

Peter G. Bruce, Jan Nowinski, Fiona M. Gray, Colin A. Vincent

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

The polymer electrolyte PEO:La(ClO₄)₃ has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg²⁺, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

Original language	English
Pages (from-to)	231-234
Number of pages	4
Journal	Solid State Ionics
Volume	38
Issue number	3-4
Publication status	Published - May 1990

Cite this

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abstract = "The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. {\textcopyright} 1990.",

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AU - Gray, Fiona M.

AU - Vincent, Colin A.

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N2 - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

AB - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

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M3 - Article

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JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - 3-4

ER -

An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO₄)₃

Abstract

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