An anhydrous polymer electrolyte containing trivalent cations

Poly(ethylene oxide):La(ClO4)3

Peter G. Bruce, Jan Nowinski, Fiona M. Gray, Colin A. Vincent

Research output: Contribution to journal › Article

Abstract

The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

Original languageEnglish
Pages (from-to)231-234
Number of pages4
JournalSolid State Ionics
Volume38
Issue number3-4
Publication statusPublished - May 1990

Fingerprint

Polyethylene oxides
Electrolytes
Cations
Polymers
Crystalline materials
Lanthanum
Monovalent Cations
Divalent Cations
Salts
X rays
perchlorate

Cite this

Bruce, P. G., Nowinski, J., Gray, F. M., & Vincent, C. A. (1990). An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3. Solid State Ionics, 38(3-4), 231-234.
Bruce, Peter G. ; Nowinski, Jan ; Gray, Fiona M. ; Vincent, Colin A. / An anhydrous polymer electrolyte containing trivalent cations : Poly(ethylene oxide):La(ClO4)3. In: Solid State Ionics. 1990 ; Vol. 38, No. 3-4. pp. 231-234.
@article{c58b23ae4758491ea290524c714833a1,
title = "An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3",
abstract = "The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. {\circledC} 1990.",
author = "Bruce, {Peter G.} and Jan Nowinski and Gray, {Fiona M.} and Vincent, {Colin A.}",
year = "1990",
month = "5",
language = "English",
volume = "38",
pages = "231--234",
journal = "Solid State Ionics",
issn = "0167-2738",
publisher = "Elsevier",
number = "3-4",

}

Bruce, PG, Nowinski, J, Gray, FM & Vincent, CA 1990, 'An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3', Solid State Ionics, vol. 38, no. 3-4, pp. 231-234.

An anhydrous polymer electrolyte containing trivalent cations : Poly(ethylene oxide):La(ClO4)3. / Bruce, Peter G.; Nowinski, Jan; Gray, Fiona M.; Vincent, Colin A.

In: Solid State Ionics, Vol. 38, No. 3-4, 05.1990, p. 231-234.

Research output: Contribution to journal › Article

TY - JOUR

T1 - An anhydrous polymer electrolyte containing trivalent cations

T2 - Poly(ethylene oxide):La(ClO4)3

AU - Bruce, Peter G.

AU - Nowinski, Jan

AU - Gray, Fiona M.

AU - Vincent, Colin A.

PY - 1990/5

Y1 - 1990/5

N2 - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

AB - The polymer electrolyte PEO:La(ClO4)3 has been prepared and investigated. In addition to crystalline PEO, X-ray and DSC results indicate the existence of a crystalline complex between the salt and polymer. Transference number meaurements indicate that the lanthanum is immobile. The conductivities, though lower than poly(ethylene oxide) based electrolytes containing monovalent cations or Hg2+, are similar to those of other anhydrous divalent cation-based polymer electrolytes. © 1990.

UR - http://www.scopus.com/inward/record.url?scp=0025425876&partnerID=8YFLogxK

M3 - Article

VL - 38

SP - 231

EP - 234

JO - Solid State Ionics

JF - Solid State Ionics

SN - 0167-2738

IS - 3-4

ER -

Bruce PG, Nowinski J, Gray FM, Vincent CA. An anhydrous polymer electrolyte containing trivalent cations: Poly(ethylene oxide):La(ClO4)3. Solid State Ionics. 1990 May;38(3-4):231-234.

Access to Document