Aluminophosphate monoliths with high CO2-over-N2 selectivity and CO2 capture capacity

F. Akhtar, N. Keshavarzi, D. Shakarova, Ocean Cheung, N. Hedin, L. Bergström

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12 Citations (Scopus)

Abstract

Monoliths of microporous aluminophosphates (AlPO4-17 and AlPO4-53) were structured by binder-free pulsed current processing. Such monoliths could be important for carbon capture from flue gas. The AlPO4-17 and AlPO4-53 monoliths exhibited a tensile strength of 1.0 MPa and a CO2 adsorption capacity of 2.5 mmol g-1 and 1.6 mmol g-1, respectively at 101 kPa and 0°C. Analyses of single component CO2 and N2 adsorption data indicated that the AlPO4-53 monoliths had an extraordinarily high CO2-over-N2 selectivity from a binary gas mixture of 15 mol% CO2 and 85 mol% N2. The estimated CO2 capture capacity of AlPO4-17 and AlPO4-53 monoliths in a typical pressure swing adsorption (PSA) process at 20°C was higher than that of the commonly used zeolite 13X granules. Under cyclic sorption conditions, AlPO4-17 and AlPO4-53 monoliths were regenerated by lowering the pressure of CO2. Regeneration was done without application of heat, which would regenerate them to their full capacity for CO2 adsorption.

Original languageEnglish
Pages (from-to)55877-55883
Number of pages7
JournalRSC Advances
Volume4
Issue number99
DOIs
Publication statusPublished - 2014

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

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    Akhtar, F., Keshavarzi, N., Shakarova, D., Cheung, O., Hedin, N., & Bergström, L. (2014). Aluminophosphate monoliths with high CO2-over-N2 selectivity and CO2 capture capacity. RSC Advances, 4(99), 55877-55883. https://doi.org/10.1039/c4ra05009f