Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

Adam P Smalley, David G Reid, Jin Chong Tan, Gareth O Lloyd

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9 Citations (Scopus)

Abstract

There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.

Original languageEnglish
Pages (from-to)9368-9371
Number of pages4
JournalCrystEngComm
Volume15
Issue number45
DOIs
Publication statusPublished - 2013

Keywords

  • METAL-ORGANIC-FRAMEWORK
  • COORDINATION POLYMERS
  • COVALENT MODIFICATION
  • SEPARATION
  • LIGAND
  • MOFS

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