Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2

Adam P Smalley; David G Reid; Jin Chong Tan; Gareth O Lloyd

doi:10.1039/c3ce41332b

Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH₂

Adam P Smalley, David G Reid, Jin Chong Tan, Gareth O Lloyd

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.

Original language	English
Pages (from-to)	9368-9371
Number of pages	4
Journal	CrystEngComm
Volume	15
Issue number	45
DOIs	https://doi.org/10.1039/c3ce41332b
Publication status	Published - 2013

Keywords

METAL-ORGANIC-FRAMEWORK
COORDINATION POLYMERS
COVALENT MODIFICATION
SEPARATION
LIGAND
MOFS

Access to Document

10.1039/c3ce41332b

Cite this

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abstract = "There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.",

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AU - Smalley, Adam P

AU - Reid, David G

AU - Tan, Jin Chong

AU - Lloyd, Gareth O

PY - 2013

Y1 - 2013

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AB - There are relatively few metal-organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH2 leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.

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KW - COORDINATION POLYMERS

KW - COVALENT MODIFICATION

KW - SEPARATION

KW - LIGAND

KW - MOFS

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DO - 10.1039/c3ce41332b

M3 - Article

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