Ag(I) Organometallic Coordination Polymers and Capsule with Tris-allyl Cyclotriveratrylene Derivatives

Marc A. Little; Malcolm A. Halcrow; Lindsay P. Harding; Michaele J. Hardie

doi:10.1021/ic101211n

Ag(I) Organometallic Coordination Polymers and Capsule with Tris-allyl Cyclotriveratrylene Derivatives

Marc A. Little, Malcolm A. Halcrow, Lindsay P. Harding, Michaele J. Hardie

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η²-allyl, aryl, and OR groups binding to Ag(I). AgSbF₆ gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag₂L₂ capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF₄ and AgClO₄, while use of Ag(CF₃SO₃) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.

Original language	English
Pages (from-to)	9486-9496
Number of pages	11
Journal	Inorganic Chemistry
Volume	49
Issue number	20
DOIs	https://doi.org/10.1021/ic101211n
Publication status	Published - 18 Oct 2010

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η2-allyl, aryl, and OR groups binding to Ag(I). AgSbF6 gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag2L2 capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF4 and AgClO4, while use of Ag(CF3SO3) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.",

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AU - Little, Marc A.

AU - Halcrow, Malcolm A.

AU - Harding, Lindsay P.

AU - Hardie, Michaele J.

PY - 2010/10/18

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N2 - Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η2-allyl, aryl, and OR groups binding to Ag(I). AgSbF6 gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag2L2 capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF4 and AgClO4, while use of Ag(CF3SO3) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.

AB - Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η2-allyl, aryl, and OR groups binding to Ag(I). AgSbF6 gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag2L2 capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF4 and AgClO4, while use of Ag(CF3SO3) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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Ag(I) Organometallic Coordination Polymers and Capsule with Tris-allyl Cyclotriveratrylene Derivatives

Abstract

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