Activation of an alkyl C-H bond geminal to an agostic interaction: An unusual mode of base-induced C-H activation

INIS

• interactions 100%
• protons 100%
• carbenes 100%
• temperature range 0273-0400 k 50%
• hydrogen 50%
• removal 50%
• barriers 50%
• charges 50%
• ligands 50%
• labelling 50%
• deuterium 50%

Chemistry

• Base 100%
• Deprotonation 66%
• N-Heterocyclic Carbene 66%
• Isopropyl Group 33%
• Chemical Activation 33%
• Ambient Reaction Temperature 33%
• C-H Bond Activation 33%
• Deuterium 33%