AC impedance of the Li(1-x)CoO2 electrode

M. G S R Thomas; P. G. Bruce; J. B. Goodenough

AC impedance of the Li(_1-x)CoO₂ electrode

M. G S R Thomas, P. G. Bruce, J. B. Goodenough

School of Engineering & Physical Sciences

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

An equivalent circuit for a porous polycrystalline insertion electrode is presented. This model is found to be inadequate to describe the ac response of the Li_(1-x)CoO₂/LiBF₄ in propylene carbonate interface because of the formation of a Li⁺-ion conducting layer on the surface of the electrode. Lithium diffusion in the electrode is determined by three methods which all indicate a value grater than that reported for TiS₂. © 1986.

Original language	English
Pages (from-to)	794-798
Number of pages	5
Journal	Solid State Ionics
Volume	18-19
Issue number	PART 2
Publication status	Published - Jan 1986

Cite this

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title = "AC impedance of the Li(1-x)CoO2 electrode",

abstract = "An equivalent circuit for a porous polycrystalline insertion electrode is presented. This model is found to be inadequate to describe the ac response of the Li(1-x)CoO2/LiBF4 in propylene carbonate interface because of the formation of a Li+-ion conducting layer on the surface of the electrode. Lithium diffusion in the electrode is determined by three methods which all indicate a value grater than that reported for TiS2. {\textcopyright} 1986.",

author = "Thomas, \{M. G S R\} and Bruce, \{P. G.\} and Goodenough, \{J. B.\}",

year = "1986",

month = jan,

language = "English",

volume = "18-19",

pages = "794--798",

journal = "Solid State Ionics",

issn = "0167-2738",

publisher = "Elsevier B.V.",

number = "PART 2",

}

TY - JOUR

T1 - AC impedance of the Li(1-x)CoO2 electrode

AU - Thomas, M. G S R

AU - Bruce, P. G.

AU - Goodenough, J. B.

PY - 1986/1

Y1 - 1986/1

N2 - An equivalent circuit for a porous polycrystalline insertion electrode is presented. This model is found to be inadequate to describe the ac response of the Li(1-x)CoO2/LiBF4 in propylene carbonate interface because of the formation of a Li+-ion conducting layer on the surface of the electrode. Lithium diffusion in the electrode is determined by three methods which all indicate a value grater than that reported for TiS2. © 1986.

AB - An equivalent circuit for a porous polycrystalline insertion electrode is presented. This model is found to be inadequate to describe the ac response of the Li(1-x)CoO2/LiBF4 in propylene carbonate interface because of the formation of a Li+-ion conducting layer on the surface of the electrode. Lithium diffusion in the electrode is determined by three methods which all indicate a value grater than that reported for TiS2. © 1986.

UR - https://www.scopus.com/pages/publications/0021896381

M3 - Article

SN - 0167-2738

VL - 18-19

SP - 794

EP - 798

JO - Solid State Ionics

JF - Solid State Ionics

IS - PART 2

ER -

AC impedance of the Li(_1-x)CoO₂ electrode

Abstract

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