We describe a novel experimental setup that combines the advantages of both laser-induced fluorescence and cavity ring-down techniques. The simultaneous measurement of the ring-down and fluorescence signals from the same sample in a single laser beam delivers the calibration of the fluorescence measurement to gain absolute quantities: absorption cross section, sample density and fluorescence quantum yield. At the same time, the fluorescence measurement extends the dynamic range of a stand-alone cavity ring-down setup from typically three to at least six orders of magnitude. The methodology of this combined cavity-enhanced laser-induced fluorescence (CELIF) technique is developed and rigorously tested against the spectroscopy of 1,4-bis(phenylethynyl)benzene in a molecular beam and density measurements in a cell.
|Number of pages||25|
|Journal||Journal of Chemical Physics|
|Early online date||8 Aug 2013|
|Publication status||E-pub ahead of print - 8 Aug 2013|