Abstract
An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.
| Original language | English |
|---|---|
| Pages (from-to) | 20-22 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 47 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 7 Jan 2008 |
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Vaqueiro, P. (2008). A three-dimensional open-framework indium selenide: [C7H 10N][In9Se14]. Inorganic Chemistry, 47(1), 20-22. https://doi.org/10.1021/ic701995p