A three-dimensional open-framework indium selenide: [C7H 10N][In9Se14]

Paz Vaqueiro

doi:10.1021/ic701995p

A three-dimensional open-framework indium selenide: [C₇H ₁₀N][In₉Se₁₄]

Paz Vaqueiro

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40 Citations (Scopus)

Abstract

An open-framework indium selenide, [C₇H₁₀N][In ₉Se₁₄], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C ₇H₁₀N][In₉Se₁₄] contains an unusual building unit, in which corner- and edge-linked InSe₄^5- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.

Original language	English
Pages (from-to)	20-22
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	1
DOIs	https://doi.org/10.1021/ic701995p
Publication status	Published - 7 Jan 2008

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@article{259b51b7e52e4573ad6e1865fac4288a,

title = "A three-dimensional open-framework indium selenide: [C7H 10N][In9Se14]",

abstract = "An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 {\AA} diameter, results in approximately 25% of solvent-accessible void space. {\textcopyright} 2008 American Chemical Society.",

author = "Paz Vaqueiro",

year = "2008",

month = jan,

day = "7",

doi = "10.1021/ic701995p",

language = "English",

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pages = "20--22",

journal = "Inorganic Chemistry",

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T1 - A three-dimensional open-framework indium selenide

T2 - [C7H 10N][In9Se14]

AU - Vaqueiro, Paz

PY - 2008/1/7

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N2 - An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.

AB - An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.

U2 - 10.1021/ic701995p

DO - 10.1021/ic701995p

M3 - Article

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VL - 47

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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