Abstract
An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.
| Original language | English |
|---|---|
| Pages (from-to) | 20-22 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 47 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - 7 Jan 2008 |
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A three-dimensional open-framework indium selenide : [C7H 10N][In9Se14]. / Vaqueiro, Paz.
In: Inorganic Chemistry, Vol. 47, No. 1, 07.01.2008, p. 20-22.Research output: Contribution to journal › Article
TY - JOUR
T1 - A three-dimensional open-framework indium selenide
T2 - [C7H 10N][In9Se14]
AU - Vaqueiro, Paz
PY - 2008/1/7
Y1 - 2008/1/7
N2 - An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.
AB - An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.
U2 - 10.1021/ic701995p
DO - 10.1021/ic701995p
M3 - Article
VL - 47
SP - 20
EP - 22
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 1
ER -