A three-dimensional open-framework indium selenide

[C7H 10N][In9Se14]

Paz Vaqueiro

Research output: Contribution to journalArticle

Abstract

An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.

Original languageEnglish
Pages (from-to)20-22
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number1
DOIs
Publication statusPublished - 7 Jan 2008

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Thermogravimetry
Indium
Fourier Analysis
X-Ray Diffraction
Spectrum Analysis
3,5-dimethylpyridine

Cite this

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title = "A three-dimensional open-framework indium selenide: [C7H 10N][In9Se14]",
abstract = "An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 {\AA} diameter, results in approximately 25{\%} of solvent-accessible void space. {\circledC} 2008 American Chemical Society.",
author = "Paz Vaqueiro",
year = "2008",
month = "1",
day = "7",
doi = "10.1021/ic701995p",
language = "English",
volume = "47",
pages = "20--22",
journal = "Inorganic Chemistry",
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}

A three-dimensional open-framework indium selenide : [C7H 10N][In9Se14]. / Vaqueiro, Paz.

In: Inorganic Chemistry, Vol. 47, No. 1, 07.01.2008, p. 20-22.

Research output: Contribution to journalArticle

TY - JOUR

T1 - A three-dimensional open-framework indium selenide

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AU - Vaqueiro, Paz

PY - 2008/1/7

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N2 - An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.

AB - An open-framework indium selenide, [C7H10N][In 9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine and characterized by single-crystal X-ray diffraction, thermogravimetry, elemental analysis, Fourier tranform IR spectroscopy, and UV-vis diffuse reflectance. The crystal structure of [C 7H10N][In9Se14] contains an unusual building unit, in which corner- and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent-accessible void space. © 2008 American Chemical Society.

U2 - 10.1021/ic701995p

DO - 10.1021/ic701995p

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SP - 20

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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