A study of the valence shell photoelectron and photoabsorption spectra of CF3SF5

D. M P Holland, D. A. Shaw, I. C. Walker, I. J. McEwen, E. Aprá, M. F. Guest

Research output: Contribution to journalArticle

Abstract

The outer valence shell photoelectron spectrum of CF3SF 5 has been studied experimentally and theoretically. Synchrotron radiation has been used to record angle-resolved outer valence shell photoelectron spectra of CF3SF5 in the photon energy range 18-60 eV. These spectra have allowed photoelectron asymmetry parameters and branching ratios to be derived. The Outer Valence Green's Function approach has been employed to calculate the molecular orbital configuration and associated binding energies. A charge distribution analysis has also been obtained. Assignments have been proposed for the peaks observed in the photoelectron spectrum. The absolute photoabsorption cross section of CF 3SF5 has been measured from threshold to 40 eV, and strongly resembles that of SF6. Assignments, involving intravalence transitions, have been proposed for some of the principal features appearing in the photoabsorption spectrum of CF3SF5. © 2005 IOP Publishing Ltd.

Original languageEnglish
Pages (from-to)2047-2067
Number of pages21
JournalJournal of Physics B: Atomic, Molecular and Optical Physics
Volume38
Issue number12
DOIs
Publication statusPublished - 28 Jun 2005

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photoabsorption
photoelectrons
valence
charge distribution
molecular orbitals
synchrotron radiation
Green's functions
binding energy
asymmetry
thresholds
cross sections
photons
configurations
energy

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Holland, D. M P ; Shaw, D. A. ; Walker, I. C. ; McEwen, I. J. ; Aprá, E. ; Guest, M. F. / A study of the valence shell photoelectron and photoabsorption spectra of CF3SF5. In: Journal of Physics B: Atomic, Molecular and Optical Physics. 2005 ; Vol. 38, No. 12. pp. 2047-2067.
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A study of the valence shell photoelectron and photoabsorption spectra of CF3SF5. / Holland, D. M P; Shaw, D. A.; Walker, I. C.; McEwen, I. J.; Aprá, E.; Guest, M. F.

In: Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 38, No. 12, 28.06.2005, p. 2047-2067.

Research output: Contribution to journalArticle

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AU - Holland, D. M P

AU - Shaw, D. A.

AU - Walker, I. C.

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AU - Guest, M. F.

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